36210-57-8Relevant academic research and scientific papers
Angular BN-Heteroacenes with syn-Structure-Induced Promising Properties as Host Materials of Blue Organic Light-Emitting Diodes
Zhang, Wanzheng,Zhang, Fan,Tang, Ruizhi,Fu, Yubin,Wang, Xinyang,Zhuang, Xiaodong,He, Gufeng,Feng, Xinliang
, p. 3618 - 3621 (2016)
A series of novel angular BN-heteroacenes were successfully synthesized. Associated with the intrinsic syn-structures, they exhibit unique molecular alignments in a solid state and promising electronic properties, and are thus suitable as efficient nondop
Synthesis of aza-m-xylylene diradicals with large singlet-triplet energy gap and statistical analyses of their EPR spectra
Olankitwanit, Arnon,Pink, Maren,Rajca, Suchada,Rajca, Andrzej
supporting information, p. 14277 - 14288 (2014/12/11)
We describe synthesis and characterization of a derivative of aza-m-xylylene, diradical 2, that is persistent in solution at room temperature with the half-life measured in minutes (～80-250 s) and in which the triplet ground state is below the lowest sing
Intramolecular cyclization of ortho-alkynylanilines by Rh(I)-catalyzed hydroamination to yield benzo(dipyrroles)
Clentsmith, Guy K.B.,Field, Leslie D.,Messerle, Barbara A.,Shasha, Adelle,Turner, Peter
supporting information; experimental part, p. 1469 - 1471 (2009/06/08)
The methylene-bridged Rh(I) dicarbonyl complex, [Rh(bim) (CO)2+ BPh4-] (1) (bim = bis(N-methylimidazol-2-yl)methane), is an effective catalyst for the intramolecular hydroamination of selected ortho-alkynylanilines to give a range of benzo(dipyrroles).
Cyclization of acetylenic amides using a cationic rhodium(I) complex
Burling, Suzanne,Field, Leslie D.,Li, Hsiu L.,Messerle, Barbara A.,Shasha, Adelle
, p. 677 - 680 (2007/10/03)
The cationic Rh(I) dicarbonyl complex [{Rh(bim)(CO)2} +BPh4-] 1, containing a bidentate bisimidazolylmethane ligand [bim refers to bis(N-methylimidazol-2-yl)methane] acts as a catalyst for the cyclization of alkynyl amides to produce lactams and N-acyl heterocyclic compounds.
