36239-01-7

Basic information

• Product Name: [methyl(nitro)amino]methyl acetate
• Synonyms: [Methyl(nitro)amino]methyl acetate; methanol, 1-(methylnitroamino)-, acetate (ester)
• CAS NO: 36239-01-7
• Molecular Formula: C₄H₈N₂O₄
• Molecular Weight: 148.1173
• Mol File: 36239-01-7.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 274.6°C at 760 mmHg
• Flash Point: 119.9°C
• Density: 1.254g/cm³
• Vapor Pressure: 0.00535mmHg at 25°C
• Refractive Index: 1.456
• CAS DataBase Reference: [methyl(nitro)amino]methyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: [methyl(nitro)amino]methyl acetate(36239-01-7)
• EPA Substance Registry System: [methyl(nitro)amino]methyl acetate(36239-01-7)

Safety Data

• Hazardous Substances Data: 36239-01-7(Hazardous Substances Data)

Upstream product

• 108-74-7 1,3,5-trimethyl-1,3,5-triazacyclohexane 
• 108-24-7 acetic anhydride 
• 49615-05-6 methyl-nitro-piperidin-1-ylmethyl-amine 
• 134842-18-5 (methylnitroamino)methyl vinyl ether 
• 64-19-7 acetic acid 
• 1246091-58-6 MeN(CH₂N₃)2 
• 32818-80-7 1-hydroxy-2-nitro-2-azapropane 
• 75-36-5 acetyl chloride 
• 99867-90-0 N,N,N',N'-Tetramethylnitraminomethyl-ethylendiamin 
• 5754-81-4 Tris-(N-nitro-N-methyl-aminomethyl)-amin 
• 874514-90-6 4-methyl-2,6-dinitro-2,4,6-triaza-heptane 
• 50-00-0 formaldehyd 
• 598-57-2 methylnitroamine 

Downstream Products

• 128038-54-0 2-(2-nitro-2-azapropyl)-4-methylphenol 
• 128038-66-4 C₂₁H₂₀N₂O₃ 
• 128038-55-1 2,4-bis(2-nitro-2-azapropyl)-6-methylphenol 
• 128038-50-6 4-(2-nitro-2-azapropyl)phenol 
• 121033-32-7 C₉H₁₀N₆O₂ 
• 36239-04-0 2-Nitro-2-azapropyl-p-nitrobenzoat 
• 36239-05-1 N-Methyl-N-nitrobenzylamine 
• 121033-39-4 3-(2-nitro-2-azapropyl)-4-oxo-1,2,3-triazole 1-oxide 

Relevant articles and documents

Hydrazoic acid in the Mannich reaction

The possibility of the three-component condensation of hydrazoic acid and formaldehyde with primary or secondary amines, as well as with trialkylhydrazines, leading to the corresponding N-azidomethyl derivatives of amines and hydrazides was established.

New energetic materials featuring tetrazoles and nitramines - synthesis, characterization and properties

The alkylation of 2-nitro-2-azapropyl chloride (2) and deprotonated 5-amino-1H-tetrazole (3), 1H-tetrazole (4), 5-nitriminol,4H-tetrazole (5), 1-methyl-5-nitrimino-4H-tetrazole (6) and 2methyl-5-nitraminotetrazole (7) afforded the products 1.-(2-nitro-2-azapropyl)-5-aminotetrazole (8), 1-(2-nitro-2-azapropyl)-5H-tetrazole (9), 1-(2-nitro-2-azapropyl)-5- nitriminotetrazole.H2O (10a), 1-(2-nitro-2azapropyl)-S- nitriminotetrazole-EtOH (10b) 1,5-bis(2-nitro-2-azapropyl)-5-nitraminotetrazole (11), 1.-methyl-5-(2-nitro-2-azapropyl)-5-nitraminotetrazole (12), 1-methyl-4-(2-nitro-2-azapropyl)-5-nitraminotetrazole (13), 1-methyl-5-(2-nitro- 2-azapropyl)-5-aminotetrazole (14) and 2-methyl-5-(2-nitro-2-azapropyl)-5- nitraminotetrazole (15). In addition, the reaction of potassium 1-methyl-5-nitriminotetrazolate with dimethyl sulfate was investigated yielding 1,4-dimethyl-5-nitriminotetrazole (16). All products (8-16) were determined by low tempera ture single X-ray diffraction. A comprehensive characterization and description of the chemical properties (IR, Raman, and multinuclear ( 1H, 13C and 15N) NMR spectroscopy, mass spectrometry, elemental analysis and differential scanning calorimetry) is given. The heats of formation were calculated by heats of combustion measured using bomb calorimetry. With these values and the X-ray densities, several, detonation parameters (e.g. detonation pressure, detonation, velocity, heat of explosion) were computed by the EXPLO5 software. In addition, the sensitivities towards impact, friction and electrical discharge were determined.

Vinyl ethers of nitramino alcohols

The vinyl exchange reactions of nitramino alcohols with vinyl acetate in the presence of mercuric acetate and BF3 etherate and also the dehydrochlorination of 2-chloroethyl ether of 2-nitro-2-aza-1-propanol by bases in the presence of interphase transfer