36239-05-1Relevant articles and documents
Nonacidic Nitration of Secondary Amines
Bottaro, Jeffrey C.,Schmitt, Robert J.,Bedford, Clifford D.
, p. 2292 - 2294 (1987)
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N-Nitration of Secondary Amines with 4-Chloro-5-methoxy-2-nitropyridazin-3-one
Park, Young-Dae,Kim, Ho-Kyun,Kim, Jeum-Jong,Cho, Su-Dong,Kim, Sung-Kyu,Shiro, Motoo,Yoon, Yong-Jin
, p. 9113 - 9115 (2007/10/03)
N-Nitration of 4-chloro-5-substituted-pyridazin-3-one with copper nitrate trihydrate in acetic anhydride gave the corresponding 4-chloro-2-nitro-5-substituted-pyridazin-3-one. 4-Chloro-5-alkoxy-2-nitropyridazin-3-ones such as 5-methoxy (2b) and 5-ethoxy (2d) derivatives showed excellent nitro group transfer potentiality. N-Nitration of some secondary amines with 2b gave the corresponding N-nitramines under mild neutral condition in good yields.