36275-68-0

Upstream product

• 13450-91-4 gallium(III) iodide 
• 7784-34-1 arsenic trichloride 
• 7784-46-5 sodium arsenite 
• 109-99-9 tetrahydrofuran 
• 12185-10-3 phosphorous 
• 129896-75-9 tris(2,6-diisopropylphenoxy) dichloroniobium(V) 
• 12511-95-4 AsP₃ 

Downstream Products

• 61219-26-9 manganese monoarsenide 
• 118576-13-9 As₄O 
• 118576-12-8 (As₃)*(AsO) 
• 118576-15-1 As(x)O(x) 
• 10028-15-6 ozone 
• 23878-46-8 arsenic 
• 7784-34-1 arsenic trichloride 

Relevant academic research and scientific papers

Thermal decomposition behavior of sodium arsenite in the presence of carbonized β-cyclodextrin

The thermal decomposition behavior of sodium arsenite (SA) was greatly affected by carbonized β-cyclodextrin (CD), possessing the releases of four forms of gaseous arsenic molecules according to gas chromatography coupled to time-of-flight mass spectromet

Studies on syntheses and conditions of formation for LnSiAs3 compounds (Ln ≡ La, Ce, Pr)

Syntheses of Ln-Si-As compounds (Ln≡La, Ce, Pr, Nd, Sm) have been attempted using a temperature-gradient furnace by controlling the arsenic pressure. Several ternary compounds, with the composition LnSiAs3(Ln≡La-Pr), were formed. An apparatus for thermogravimetric experiments in a sealed silica tube under a controlled arsenic pressure using the temperature-gradient furnace was constructed for thermogravimetric measurements of conditions of formation for the Ln-Si-As systems between 700 and 1000°C and arsenic pressures of 10-2 to 20 atm. From these results, together with other results from differential thermal and X-ray analyses, the conditions for the formation of these ternary compounds were obtained.

Iron β-diiminate complexes with As2-, As4- And As8-ligands

Different substituents at the β-diiminato ligand in low-valent [LFe(tol)] (L = β-diiminato) complexes fundamentally change their reactivity towards yellow arsenic. By using dmp (2,6-dimethylphenyl) as flanking groups, the tetranuclear complexes [(LFe)4As8

Stabilization of tetrahedral P4 and As4 molecules as guests in polymeric and spherical environments

As you like it: [Ag(η2-As4)2] +[pftb]- can be used to store yellow arsenic (As 4). From it, As4 can be easily released to give concentrated, light-stable solutions. These As

Triple-bond reactivity of an AsP complex intermediate: Synthesis stemming from molecular arsenic, As4

While P4 is the stable molecular form of phosphorus, a recent study illustrated the possibility of P2 generation for reactions in organic media under mild conditions. The heavier group 15 element arsenic can exist as As4 molecules, but As4 cannot be stored as a pure substance because it is both light-sensitive and reverts thermally to its stable, metallic gray form. Herein we report As4 activation giving rise to a μ-As2 diniobium complex, serving in turn as precursor to a terminal arsenide anion complex of niobium. Functionalization of the latter provides the new AsPNMes* ligand, which when complexed with tungsten pentacarbonyl elicits extrusion of the (AsP)W(CO)5 molecule as a reactive intermediate. Trapping reactions of the latter with organic dienes are found to furnish double Diels-Alder adducts in which the AsP unit is embedded in a polycyclic organic framework. Thermal generation of (AsP)W(CO)5 in the presence of the neutral terminal phosphide complex P=Mo(N[ iPr]Ar)3 leads to the cyclo-AsP2 complex (OC)5W(cyclo-AsP2)Mo(N[iPr]Ar)3. The (AsP)W(CO)5 trapping products were crystallized and characterized by X-ray diffraction methods, and computational methods were applied for analysis of the As-As and As-P bonds in the complexes.

Properties and reactivity patterns of AsP3: An experimental and computational study of group 15 elemental molecules

Facile synthetic access to the isolable, thermally robust AsP3 molecule has allowed for a thorough study of its physical properties and reaction chemistry with a variety of transition-metal and organic fragments. The electronic properties of As