36613-93-1

Usage

Uses

Used in Food and Beverage Industry:
Methyl 2-cyclohexylbutanoate is used as a flavoring agent for its sweet, fruity odor, enhancing the taste and aroma of various food products such as candies, baked goods, and beverages.
Used in Perfume and Fragrance Industry:
Methyl 2-cyclohexylbutanoate is used as a component in perfumes and fragrances due to its pleasant scent, contributing to the overall fragrance profile of these products.
Used in Personal Care and Household Products:
Methyl 2-cyclohexylbutanoate is used in personal care and household products for its sweet, fruity scent, adding a pleasant aroma to these products and making them more appealing to consumers.

Upstream product

• 67-56-1 methanol 
• 6051-00-9 2-cyclohexyl-butyric acid 
• 623-43-8 crotonic acid methyl ester 
• 110-82-7 cyclohexane 
• 14352-61-5 methyl cyclohexylacetate 
• 75-03-6 ethyl iodide 
• 5292-21-7 Cyclohexylacetic acid 

Downstream Products

• 36588-65-5 C₂₂H₂₆O₂ 
• 33204-52-3 α-Aethyl-cyclohexanaethanol 
• 33856-70-1 2-Cyclohexyl-butanal 
• 6293-41-0 4-cyclohexyl-hexanoic acid 
• 592509-72-3 4-cyclohexyl-hexanoic acid ethyl ester 
• 592509-62-1 5-cyclohexyl-2-oxo-heptanoic acid methyl ester 
• 592509-73-4 6-cyclohexyl-3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-octanenitrile 

Relevant academic research and scientific papers

Investigation on the regioselectivities of intramolecular oxidation of unactivated C-H bonds by dioxiranes generated in Situ

We found that dioxiranes generated in situ from ketones 1-6 and Oxone underwent intramolecular oxidation of unactivated C-H bonds at δ sites of ketones to yield tetrahydropyrans. From the trans/cis ratio of oxidation products 1a and 2a as well as the retention of the configuration at the δ site of ketone 5, we proposed that the oxidation reaction proceeds through a concerted pathway under a spiro transition state. The intramolecular oxidation of ketone 6 showed the preference for a tertiary δ C-H bond over a secondary one. This intramolecular oxidation method can be extended to the oxidation of the tertiary γ′ C-H bond of ketones 9 and 10. For ketone 11 with two δ C-H bonds and one γ′ C-H bond linked respectively by a sp3 hydrocarbon tether and a sp2 ester tether, the oxidation took place exclusively at the δ C-H bonds. Finally, by introducing proper tethers, regioselective hydroxylation of steroid ketones 12-14 have been achieved at the C-17, C-16, C-3, and C-5 positions.

Thermal Addition of Alkanes to Alkenes, IV. Regioselectivity in the Addition of Cyclohexane to 1,2-Disubstituted Alkenes

Alkanes can be added to alkenes in a free radical chain reaction ("ane reaction").Regioselectivity in the addition of cyclohexane to (E)-3-alkyl substituted methyl acrylates have been measured at 300-450C.The ratio of the two regioisomers 3 and 4 shows a correlation with steric substituent constants Es.Relative rates of the addition of cyclohexyl radical to the alkene and β-scission of the adduct radical versus H-transfer from cyclohexane are determining the ratio of the regioisomers.A minor temperature dependence of regioselectivity has been observed.In relation to the products 3 and 4, ane reaction at a temperature of 450C can be more selective than radical addition reaction at room temperature.Regioselectivity of the addition of cyclohexane to methyl cinnamate at 360-420C shows a slight polar substituent effect.Electron withdrawing substituents have been shown to increase product ratio 4/3.

HOCHDRUCK-HOCHTEMPERATUR-REAKTIONEN IN EINEM STROEMUNGSREAKTOR-VI. THERMISCHE ADDITION VON ALKANEN AN ALKENE

The thermal Anti-Markownikow-addition of alkanes to activated and desactivated alkenes ("direkte substituierende Addition", "Ane-reaction") at 650-723 K and reaction times of 1-10 min. is described.