36710-80-2

Basic information

• Product Name: Pyridine, 2-(4-methoxyphenyl)-, 1-oxide
• CAS NO: 36710-80-2
• Molecular Formula: C12H11NO2
• Molecular Weight: 201.225
• Mol File: 36710-80-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-(4-methoxyphenyl)-, 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-(4-methoxyphenyl)-, 1-oxide(36710-80-2)
• EPA Substance Registry System: Pyridine, 2-(4-methoxyphenyl)-, 1-oxide(36710-80-2)

Safety Data

• Hazardous Substances Data: 36710-80-2(Hazardous Substances Data)

Upstream product

• 93-59-4 Perbenzoic acid 
• 5957-90-4 4-(2-pyridinyl)anisole 
• 14774-77-7 p-methoxyphenyllithium 
• 694-59-7 pyridine N-oxide 
• 66107-29-7 4-methoxyphenyl triflate 
• 5720-07-0 4-methoxyphenylboronic acid 
• 100-09-4 4-methoxybenzoic acid 
• 14305-17-0 2-bromopyridine-N-oxide 
• 856851-28-0 4-chloro-2-(4-methoxyphenyl)pyridine 
• 26452-80-2 2,4-dichloropyridine 
• 824-40-8 2-pyridinecarboxylic acid N-oxide 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 696-62-8 para-iodoanisole 
• 3899-91-0 4-methoxyphenyl p-toluenesulfonate 

Downstream Products

• 856851-28-0 4-chloro-2-(4-methoxyphenyl)pyridine 
• 851595-31-8 2-chloro-6-(4-methoxyphenyl)pyridine 
• 5957-90-4 4-(2-pyridinyl)anisole 
• 33777-95-6 2-(4-methoxyphenyl)-6-phenylpyridine 
• 1415693-89-8 1,1,1-trifluoro-N-(6-(4-methoxyphenyl)pyridin-2-yl)-N-phenylmethanesulfonamide 

Relevant articles and documents

Visible-Light-Induced ortho-Selective Migration on Pyridyl Ring: Trifluoromethylative Pyridylation of Unactivated Alkenes

The photocatalyzed ortho-selective migration on a pyridyl ring has been achieved for the site-selective trifluoromethylative pyridylation of unactivated alkenes. The overall process is initiated by the selective addition of a CF3 radical to the alkene to provide a nucleophilic alkyl radical intermediate, which enables an intramolecular endo addition exclusively to the ortho-position of the pyridinium salt. Both secondary and tertiary alkyl radicals are well-suited for addition to the C2-position of pyridinium salts to ultimately provide synthetically valuable C2-fluoroalkyl functionalized pyridines. Moreover, the method was successfully applied to the reaction with P-centered radicals. The utility of this transformation was further demonstrated by the late-stage functionalization of complex bioactive molecules.

Decarboxylative Arylation of Pyridine 1-Oxides and Anilides with Benzoic Acid via Palladium-Catalyzed C–H Functionalization

A novel method for the palladium-catalyzed decarboxylative ortho C–H bond arylation of pyridine 1-oxides and anilides with benzoic acids as aryl sources is described. The established methodology provides a direct approach for the synthesis of 2-arylpyridine 1-oxides and 2-aryl anilides in good isolated yields.

Palladium-catalyzed direct C-H arylation of pyridine N-oxides with potassium aryl- and heteroaryltrifluoroborates

An efficient ligand-free Pd(OAc)2-catalyzed selective arylation of pyridine N-oxides using potassium (hetero)aryltrifluoroborates as coupling partners via C-H bond activation was achieved in the presence of TBAI. This approach has a broad subst