36841-98-2Relevant academic research and scientific papers
Directed Zincation with TMPZnCl·LiCl and Further Functionalization of the Tropolone Scaffold
Haas, Diana,Sustac-Roman, Daniela,Schwarz, Sophia,Knochel, Paul
, p. 6380 - 6383 (2016)
The directed zincation of tropolone derivatives was achieved using TMPZnCl·LiCl. Various functionalizations of the zincated intermediates by halogenation, acylation, allylation, and Negishi cross-coupling were successfully performed. Additionally, 1,8-conjugate addition-elimination reactions with a variety of arylmagnesium and secondary alkylzinc reagents were carried out to further elaborate the tropolone core.
Anodic oxidation of cycloheptatriene systems and its application to the synthesis of non-benzenoid aromatic compounds
Shono, Tatsuya,Nozoe, Tetsuo,Maekawa, Hirofumi,Yamaguchi, Yoshihide,Kanetaka, Shinya,Masuda, Haruhisa,Okada, Toshio,Kashimura, Shigenori
, p. 593 - 603 (2007/10/02)
Anodic oxidation of cycloheptatrienes has been found to be one of the most powerful key tools for the preparation of a variety of non-benzenoid aromatic compounds such as tropylium salts, tropones, tropolones, 2H-cyclohepta[b]furan-2-ones, and azulenes.
PHOTOCHEMICAL REACTIONS OF DIALKYLBORYLTROPOLONATE COMPLEXES
Okada, Keiji,Inokawa, Haruki,Oda, Masaji
, p. 4395 - 4398 (2007/10/02)
Irradation of a benzene solution of dialkylboryltropolonates produced alkyl migrated tropolone and tropone derivatives.The product distribution and the mechanism of this rearrangement were investigated.
