37097-18-0Relevant academic research and scientific papers
Facile and efficient synthesis of 14-alkyl- or aryl-14-H-dibenzo[a,j] xanthenes using sulfonyl-functionalized ionic liquids
Kumari, Pratibha,Yathindranath, Vinith,Chauhan
, p. 637 - 648 (2008)
An efficient, simple, and rapid synthesis of 14-alkyl-or aryl-14-H-dibenzo[a,j]xanthenes is reported by one-pot condensation of 2-naphthol with alkyl or aryl aldehydes in the presence of sulfonyl- functionalized acidic ionic liquids at 125°C. Copyright Ta
Design and characterization of [(Et)3?N-H]FeCl4 as a nanomagnetic ionic liquid catalyst for the synthesis of xanthene derivatives under solvent-free conditions
Ezabadi, Ali,Salami, Masoumeh
, (2022/01/24)
The triethylamine-based nanomagnetic ionic liquid, [(Et)3?N-H]FeCl4, was synthesized, and its structural and chemical characteristics were detected. The thermogravimetric analysis indicated its high thermal stability with a decomposi
Solvent-free synthesis of 14-aryl-14H-dibenzo[a-j]xanthenes using Fe3O4@Al2O3@SiO2@Fe2O3 as a green catalyst
Darya, Naghmeh,Tajik, Hassan
supporting information, p. 3546 - 3564 (2021/11/04)
We report, a novel, green, nano-sized particles as a sandwich nano-capsule multilayer catalyst (SNC@MC) [Fe3O4@Al2O3@SiO2@Fe2O3] for the efficacious one-pot synthesis of 14-aryl-
Fabrication of activated carbon sulfuric acid as an excellent and novel solid acid catalyst, evaluating its catalytic activity in synthesizing 1,8-dioxo-octahydroxanthenes and 14-aryl-14H-dibenzo[a,j]xanthenes
Marandi, Alireza,Koukabi, Nadiya,Zolfigol, Mohammad Ali
, p. 3145 - 3163 (2021/05/03)
In this work, for the first time, a novel and innovative procedure has been utilized to chemically functionalize activated carbon (AC) based on the sulfonation reaction, which can be used in catalytic reactions as a strong solid acid. For this aim, AC mus
Alkene-modified Fe3O4 nanoparticle-mediated construction of functionalized mesoporous poly(ionic liquid)s: Synergistic catalysis of mesoporous confinement effect and hydrogen proton for organic transformations
Liu, Zhong-Qiu,Li, Sheng-Nan,Zeng, Qing-Shuai,Liu, Yu-Jing,You, Jin-Mao,Ying, An-Guo
, (2021/02/21)
The preparation of mesoporous poly(ionic liquid)s (MPILs) is critically fundamental for the design of heterogeneous catalysts, whereas traditional methods are difficult to obtain these materials with both well-defined mesoporous structure and unique functionality. Here, HClO4-functionalized MPILs with well-defined mesoporous structure were successfully fabricated, in which the alkene-modified Fe3O4 nanoparticles as structural reinforcer play a vital role for mesoporous structure formation. The MPILs were characterized by N2 adsorption/desorption, scanning electron microscope (SEM), transmission Electron Microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and vibration sample magnetometry (VSM), and the results confirm that MPILs possess moderate surface area, well-defined mesoporosity, abundant active ionic centers, as well as efficient magnetic recovery. The resulting MPILs show excellent catalytic activity for condensation reaction and Knoevenagel condensation. The kinetic study reveals that the excellent catalytic activity of MPILs is attributed to the synergistic catalysis of mesoporous confinement effect and hydrogen proton from MPILs, albeit with mass transfer resistance produced by mesoporous channels. Further, the catalyst can be recovered using an external magnetic field and reused at least 10 times without a considerable decrease in its catalytic activity. Finally, alkene-modified Fe3O4 nanoparticle-mediated mesoporous construction promotes a textural engineering approach to the development of novel mesoporous materials for other applications.
A rapid and quantitative synthesis of xanthene derivatives using sulfonated graphitic carbon nitride under ball‐milling
Azizi, Najmedin,Ghaffarzadeh, Mohammad,Qareaghaj, Omid Hosseinchi
, (2021/07/02)
A truly green, solventless, and fast protocol for the quantitative preparation of biologically active xanthene derivatives with 10 mol% sulfonated graphitic carbon nitride (Sg─CN) as a heterogeneous acidic catalyst was developed. Excellent yields, low cost, solvent‐free conditions, high catalytic activity, reusability of the catalyst, simple workup, and heterogeneous carbon‐based catalyst make the present method particularly attractive from a green chemistry perspective.
Nano-ZnO Impregnated on Starch—A Highly Efficient Heterogeneous Bio-Based Catalyst for One-Pot Synthesis of Pyranopyrimidinone and Xanthene Derivatives as Potential Antibacterial Agents
Amininia,Pourshamsian,Sadeghi
, p. 1279 - 1288 (2020/10/02)
Abstract: A new method has been proposed for the synthesis of pyranopyrimidinone andxanthene derivatives using zinc oxide–starch nanocomposite as catalyst undermicrowave irradiation. The ZnO–starch nanocomposite was characterized by X-raydiffraction and s
Br?nsted Acidic Ionic Liquid-Catalyzed Synthesis of 14-Aryl-14H-dibenzo[a,j]xanthenes with Controlled Microwave Heating under Solvent-Free Conditions
Huynh, C. C.,Le, T. N.,Tran, P. H.
, p. 504 - 508 (2020/04/29)
Abstract: 1-Methyl-3-sulfo-1H-imidazol-3-ium chloride([Msim]Cl) catalyzed the condensation of β-naphthol with aromatic aldehydesunder microwave irradiation. This method is efficient to synthesizedibenzoxanthene derivatives in excellent yields, and the cat
Novel ionic liquid [Et3N-SO3H][MeSo3]: Synthesis, characterization and catalytic performance for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes
Sadeghi-Takallo, Masoud,Zare, Abdolkarim
, p. 69 - 76 (2019/03/21)
The main aim of this work is introducing a novel protic acidic ionic-liquid catalyst for organic synthesis. Thus, N,N-diethyl-N-sulfoethanaminium methanesulfonate ([Et3N-SO3H][MeSO3]) was synthesized by the reaction of triethylamine with chlorosulfonic ac
