371-22-2Relevant articles and documents
Preservation of the Coordination State of the Phosphorus Atoms in Tetraalkyl Pyrophosphites in Their Reaction with Tetraethylammonium Tetrafluoroborate
Romakhin,Nikitin
, p. 1580 - 1582 (2007/10/03)
Tetraalkyl pyrophosphites under mild conditions (in a polar aprotic solvent at 25-50°C or heating to 200°C without solvent) react with tetraethylammonium tetrafluoroborate to give an equimolar mixture of dialkyl phosphorofluoridite and dialkyl ethyl phosphite, i.e., both the pyrophosphite phosphorus atoms preserve their coordination number 3. A mechanism of the reaction is proposed.
Reactions of phosphorous esters with carboxylic acid chlorides and fluorides
Gazizov, T. Kh.,Belyalov, R. U.,Pudovik, A. N.
, p. 673 - 676 (2007/10/02)
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