4894-60-4Relevant articles and documents
Selective synthesis of organophosphites
-
Page 9-10, (2008/06/13)
Disclosed herein is a process for the selective synthesis of triorganophosphites intermediates, including chloridites and dichloridites, from PX3 (X=Cl, Br or I), alcoholos and triorganoamines where alcohol and triorganoamine are added either (a) separately and concurrently, or (b) alternating equimolar portions of amine and alcohol.
Phosphitylation via the Mitsunobu reaction
Grice, I. Darren,Harvey, Peta J.,Jenkins, Ian D.,Gallagher, Michael J.,Ranasinghe, Millagahamada G.
, p. 1087 - 1090 (2007/10/03)
Treatment of a dialkyl phosphite with triphenylphosphine and diisopropyl azodicarboxylate in toluene, followed by addition of an alcohol, results in the formation of the corresponding trialkyl phosphite. Similarly, dialkyl phosphonites can be synthesised from monoalkyl phosphites (alkyl phosphinates).
N-PHOSPHORYLATED 1,2-AZAPHOSPHETIDINES
Gubnitskaya, E. S.,Peresypkina, L. P.,Parkhomenko, V. S.
, p. 1779 - 1785 (2007/10/02)
-