37101-10-3Relevant academic research and scientific papers
Novel reaction of [bis(acyloxy)iodo]arenes
Sheremetev, Aleksei B.,Konkina, Svetlana M.
, p. 277 - 278 (2007/10/03)
The reaction of [(diacetoxy)iodo]benzene with furazan dicarboxylic acid was accompanied by a novel decarboxylative ring-cleavage reaction; the cyanogen N-oxide, reactive intermediate generated in the process, was dimerised or trapped by a dipolarophile.
Synthesis and reactivity of furazanyl- and furoxanyldiazonium salts
Rakitin, O. A.,Zalesova, O. A.,Kulikov, A. S.,Makhova, N. N.,Godovikova, T. I.,Khmel'nitskii, L. I.
, p. 1865 - 1870 (2007/10/02)
Diazotization of aminofurazans (1) and 4-aminofuroxans (2) with nitrosylsulfuric acid in a mixture of conc.H2SO4 and H3PO4 has been studied and offered as a general method for preparing furazanyl- (3) and furoxanyldiazonium (4) salts.It has been shown tha
A Novel and Efficient Method for the Preparation of α-Hydroxyimino Carbonyl Compounds from α,β-Unsaturated Carbonyl Compounds with Butyl Nitrite and Phenylsilane Catalyzed by a Cobalt(II) Complex
Kato, Koji,Mukaiyama, Teruaki
, p. 2948 - 2953 (2007/10/02)
Various α,β-unsaturated carbonyl compounds, such as α,β-unsaturated esters, α,β-unsaturated ketones, α,β-unsaturated nitriles, and α,β-unsaturated amides, were directly converted to the corresponding α-hydroxyimino carbonyl compounds in high yields on treatment with butyl nitrite and phenylsilane in the presence of a catalytic amount of N,N'-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminatocobalt(II) complex under mild conditions.
INVESTIGATION OF THE MECHANISM OF FORMATION OF HETEROCYCLES BY NMR SPECTROSCOPY. V. 3-AMINO-4-METHYLFURAZAN
Vergizov, S. N.,Selivanov, S. I.,Mel'nikova, S. F.,Ershov, B. A.,Tselinskii, I. V.
, p. 374 - 377 (2007/10/02)
The kinetics of the reaction of hydroxyiminoacetone with hydroxylamine were studied by PMR spectroscopy.The formation of 3-amino-4-methylfurazan is a multistage process; the intermediate products are methylglyoxime, methylfurazan, α-hydroxyiminopropionitrile, and methylaminoglyoxime, and the side product is α-hydroxyiminopropionamide.
