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372-19-0

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372-19-0 Usage

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Uses

3-Fluoroaniline is used in the preparation of acetic acid-(3-fluoro-anilide by reacting with acetic acid anhydride. Further, it serves as a reagent in the preparation of radamide analogs as Grp94 inhibitors, which has potential to be antitumor agents.

Definition

ChEBI: A derivative of aniline in which the hydrogen at position 3 has been substituted by fluorine. It is used as a pharmaceutical intermediate.

Check Digit Verification of cas no

The CAS Registry Mumber 372-19-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,7 and 2 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 372-19:
(5*3)+(4*7)+(3*2)+(2*1)+(1*9)=60
60 % 10 = 0
So 372-19-0 is a valid CAS Registry Number.
InChI:InChI=1/C6H6FN/c7-5-2-1-3-6(8)4-5/h1-4H,8H2

372-19-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 25g

  • 284.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 100g

  • 1128.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 500g

  • 4506.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 25g

  • 284.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 100g

  • 1128.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 500g

  • 4506.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 25g

  • 284.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 100g

  • 1128.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 500g

  • 4506.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 25g

  • 284.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 100g

  • 1128.0CNY

  • Detail
  • Alfa Aesar

  • (A14228)  3-Fluoroaniline, 98+%   

  • 372-19-0

  • 500g

  • 4506.0CNY

  • Detail

372-19-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-fluoroaniline

1.2 Other means of identification

Product number -
Other names 3-FLUORO-PHENYLAMINE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:372-19-0 SDS

372-19-0Relevant articles and documents

Biomass Sucrose-Derived Cobalt@Nitrogen-Doped Carbon for Catalytic Transfer Hydrogenation of Nitroarenes with Formic Acid

Yuan, Man,Long, Yu,Yang, Jin,Hu, Xiwei,Xu, Dan,Zhu, Yangyang,Dong, Zhengping

, p. 4156 - 4165 (2018)

Fabrication of non-noble metal-based heterogeneous catalysts by a facile and cost-effective strategy for ecofriendly catalytic transfer hydrogenation (CTH) is of great significance for organic transformations. A cobalt@nitrogen-doped carbon (Co@NC) catalyst was prepared from renewable biomass-derived sucrose, harmless melamine, and earth-abundant Co(AcO)2 as the precursor materials by hydrothermal treatment and carbonization. Co nanoparticles (NPs) were coated with NC shells and uniformly embedded in the NC framework. The as-obtained Co@NC-600 (carbonized at 600 °C) catalyst exhibited excellent catalytic efficiency for CTH of various functionalized nitroarenes with formic acid (FA) as hydrogen donor in aqueous solution. The uniformly incorporated N atoms in the C matrix and the encapsulated Co NPs showed synergistic effects in the CTH reactions. A mechanistic analysis indicated that the protons from FA were activated by Co sites after being captured by N atoms, and then reacted with nitroarenes adsorbed on the surface of the catalysts to generate the corresponding aromatic amines. Moreover, the catalyst showed excellent durability and reusability without obvious decrease in activity even after five reaction cycles. Thus, the study reported herein provides a cost-effective, sustainable strategy for fabrication of biomass-derived non-noble metal-based catalysts for green and efficient catalytic transformations.

Minimization of Back-Electron Transfer Enables the Elusive sp3 C?H Functionalization of Secondary Anilines

Zhao, Huaibo,Leonori, Daniele

supporting information, p. 7669 - 7674 (2021/03/08)

Anilines are some of the most used class of substrates for application in photoinduced electron transfer. N,N-Dialkyl-derivatives enable radical generation α to the N-atom by oxidation followed by deprotonation. This approach is however elusive to monosubstituted anilines owing to fast back-electron transfer (BET). Here we demonstrate that BET can be minimised by using photoredox catalysis in the presence of an exogenous alkylamine. This approach synergistically aids aniline SET oxidation and then accelerates the following deprotonation. In this way, the generation of α-anilinoalkyl radicals is now possible and these species can be used in a general sense to achieve divergent sp3 C?H functionalization.

Rhodium nanoparticles supported on 2-(aminomethyl)phenols-modified Fe3O4 spheres as a magnetically recoverable catalyst for reduction of nitroarenes and the degradation of dyes in water

Chen, Tian,Chen, Zhangpei,Hu, Jianshe,Lv, Kexin,Reheman, Aikebaier,Wang, Gongshu

, (2021/06/18)

A magnetic nanostructured catalyst (Fe3O4@SiO2-Amp-Rh) modified with 2-(aminomethyl)phenols (Amp) was designed and prepared, which is used to catalyze the reduction of aromatic nitro compounds into corresponding amines and the degradation of dyes. The 2-aminomethylphenol motif plays a vital role in the immobilization of rhodium nanoparticles to offer extraordinary stability, which has been characterized by using various techniques, including transmission electron microscopy (TEM), thermal gravimetric analyzer (TGA), X-Ray Diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). A variety of nitroaromatic derivatives have been reduced to the corresponding anilines in water with up to yields of 99% within 1?h at room temperature. In addition, the catalyst system is effective in catalyzing the reduction of toxic pollutant 4-nitrophenol and the degradation of MO, MB and RhB dyes. Importantly, this catalyst Fe3O4@SiO2-Amp-Rh can be easily recovered by an external magnetic field because of the presence of magnetic core of Fe3O4, and the activity of Fe3O4@SiO2-Amp-Rh does not decrease significantly after 7 times’ recycling, which indicates that the catalyst performed high reactivity as well as stability. Graphical abstract: [Figure not available: see fulltext.]

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