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372-20-3

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372-20-3 Usage

Chemical Properties

colourless to light yellow liquid

Uses

3-Fluorophenol is a reactant used in organic synthesis.

Check Digit Verification of cas no

The CAS Registry Mumber 372-20-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,7 and 2 respectively; the second part has 2 digits, 2 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 372-20:
(5*3)+(4*7)+(3*2)+(2*2)+(1*0)=53
53 % 10 = 3
So 372-20-3 is a valid CAS Registry Number.
InChI:InChI=1/C6H5FO/c7-5-2-1-3-6(8)4-5/h1-4,8H

372-20-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Fluorophenol

1.2 Other means of identification

Product number -
Other names Phenol,3-fluoro

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:372-20-3 SDS

372-20-3Relevant articles and documents

Process development and manufacture of potassium 2-fluoro-6-hydroxyphenyltrifluoroborate

Pawar, Lokesh,Jayaramaiah, Ramesh,Krishnan, Baburaj,Arunachalampillai, Athimoolam,Chen, Ying,Parsons, Andrew T.,Robinson, Jo Anna,Tedrow, Jason S.

, p. 4266 - 4270 (2019)

The development of a phase-appropriate manufacturing-scale synthesis of potassium 2-fluoro-6-hydroxyphenyltrifluoroborate was achieved. Investigations into improving the yield and robustness indicated that pH of the reaction medium is a critical process parameter. Additional development resulted in replacing tartaric acid with citric acid, resulting in improved process robustness and enabling scale-up to >10 kg.

Method for hydrolyzing diarylether compound to generate aryl phenol compound

-

Paragraph 0146-0149, (2021/09/29)

The invention discloses a method for hydrolyzing a diarylether compound to generate an arylphenol compound. According to the method, visible light is utilized to excite a photosensitizer for catalysis. In a reaction solvent, the raw material in the formula (1) breaks a C (sp2)-O bond under the auxiliary action of acid, and hydrolysis is performed to obtain the bimolecular aryl phenol compounds in the formula (3) and the formula (4). The method can catalyze the reaction at room temperature, is green and environment-friendly, and is easy to operate; the universality is wide, the reaction yield is relatively high, and the tolerance of functional groups is strong; the synthesis method not only can realize small-scale hydrolysis conversion of various diarylether compounds, but also can realize hydrolysis of herbicidal ether, triclosan and a lignin template substrate, and even can realize large-scale hydrolysis of triclosan and the lignin template substrate to realize gram-level degradation. A new strategy is provided for recovering phenol derivatives through lignin hydrolysis, degrading pesticides and purifying wastewater containing a degerming agent or herbicide. The method has wide application prospect and use value.

Nickel Hydride Catalyzed Cleavage of Allyl Ethers Induced by Isomerization

Kathe, Prasad M.,Berkefeld, Andreas,Fleischer, Ivana

supporting information, p. 1629 - 1632 (2021/02/09)

This report discloses the deallylation of O - and N -allyl functional groups by using a combination of a Ni-H precatalyst and excess Bronsted acid. Key steps are the isomerization of the O - or N -allyl group through Ni-catalyzed double-bond migration followed by Bronsted acid induced O/N-C bond hydrolysis. A variety of functional groups are tolerated in this protocol, highlighting its synthetic value.

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