3726-45-2Relevant academic research and scientific papers
A novel reduction of polycarboxylic acids into their corresponding alkanes using n-butylsilane or diethylsilane as the reducing agent
Nimmagadda, Rama D.,McRae, Christopher
, p. 3505 - 3508 (2007/10/03)
A convenient one-pot reaction has been developed for the reduction of polycarboxylic acids on aliphatic and aromatic systems to their corresponding alkanes. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.
POLYMETHYLENCYCLOHEXANE AUS EXOCYCLISCHEN ALLENEN DURCH THERMISCHE UMLAGERUNG
Lenk, Winfried,Hopf, Henning
, p. 4073 - 4076 (2007/10/02)
1,4-Bis(ethenylidene)cyclohexane (8) and 1-ethenylidene-4-methylenecyclohexane (15) have been prepared and thermally isomerized to 1,2,3,4-tetra- (13) and 1,2,4-trimethylenecyclohexane (18), respectively, at 500 deg C in a flow system.It is proposed that
