373-14-8

Basic information

• Product Name: 1-FLUOROHEXANE
• Synonyms: 1-fluoro-hexan;1-hexylfluoride;Fluorohexane;hexane,1-fluoro-;Hexylfluorid;HEXYL FLUORIDE;1-FLUOROHEXANE;N-HEXYL FLUORIDE
• CAS NO: 373-14-8
• Molecular Formula: C₆H₁₃F
• Molecular Weight: 104.17
• EINECS: 206-763-8
• Product Categories: Organics
• Mol File: 373-14-8.mol
• Article Data: 6

Chemical Properties

• Melting Point: -103°C
• Boiling Point: 93 °C
• Flash Point: 81 °F
• Appearance: clear colorless liquid
• Density: 0.8 g/mL at 25 °C(lit.)
• Vapor Pressure: 60.6mmHg at 25°C
• Refractive Index: n20/D 1.3755(lit.)
• Storage Temp.: Flammables area
• CAS DataBase Reference: 1-FLUOROHEXANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-FLUOROHEXANE(373-14-8)
• EPA Substance Registry System: 1-FLUOROHEXANE(373-14-8)

Safety Data

• Hazard Codes: T,F
• Statements: 10-23/24/25-36/37/38
• Safety Statements: 16-26-36/37/39-45
• RIDADR: UN 2929 6.1/PG 2
• WGK Germany: 3
• RTECS: MO3675000
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 373-14-8(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless liquid

InChI:InChI=1/C6H13F/c1-2-3-4-5-6-7/h2-6H2,1H3

Upstream product

• 544-10-5 1-Chlorohexane 
• 111-25-1 1-bromo-hexane 
• 16156-50-6 n-hexyl methanesulfonate 
• 81956-87-8 (η(5)-C5Me5)2HfH2 
• 559-40-0 octaperfluorocyclopentene 
• 107-21-1 ethylene glycol 
• 111-46-6 diethylene glycol 
• 110-54-3 hexane 
• 111-27-3 hexan-1-ol 
• 4665-33-2 2-hexyl-1,1-diphenyl-isourea; hydrofluoride 
• 5337-36-0 trihexyl borate 
• 3839-35-8 4-methylbenzenesulfonic acid n-hexylester 

Downstream Products

• 1595-01-3 1-hexyl-4-methyl-benzene 
• 110-54-3 hexane 
• 18589-27-0 2-iodohexane 
• 638-45-9 1-Iodohexane 
• 1077-16-3 hexylbenzene 
• 4468-42-2 3-phenylhexane 
• 6031-02-3 2-phenylhexane 

Relevant articles and documents

Molybdenum oxide-mediated facile aliphatic nucleophilic fluorination

A facile aliphatic nucleophilic fluorination with cesium fluoride in the presence of molybdenum oxide as a catalyst has been demonstrated. Reactivity of molybdenum oxide in nanocrystal form was found to be chemoselective in the presence of water. Furthermore, the reaction is highly specific with alkyl sulfonate substrates.

Activation of aromatic, aliphatic, and olefinic carbon-fluorine bonds using Cp*2HfH2

The hafnium hydride Cp*2HfH2 is reacted with a series of fluorocarbons to examine the scope of C-F bond activation. Aromatic, vinylic, and aliphatic C-F bonds all show some degree of reactivity, and possible mechanisms are discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

Thermically-Initiated Fluorinations at Saturated Carbon Atoms with Xenon Difluoride

The heating of several hydrocarbons with xenon difluoride at 95-120 deg C in stainless steel reactor equipped with teflon jackets resulted in mono-, di-, and trisubstituted products.