3739-97-7

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 19493-09-5 Methylenetriphenylphosphorane 
• 3739-98-8 triphenyl(trimethylsilylmethyl)phosphonium iodide 
• 4206-67-1 iodo(trimethylsilyl)methane 

Downstream Products

• 36121-20-7 Triphenylmethyl-fluorphosphoran 
• 101305-47-9 1,6-Bis-(triphenyl-λ⁵-phosphanylidene)-hexane-2,5-dione 
• 63636-63-5 ((E)-3-Methyl-buta-1,3-dienyl)-triphenyl-phosphonium; bromide 
• 89353-62-8 (Z,Z,Z)-3,6,9-nonadecatriene 
• 129750-74-9 (3Z, 6Z, 9E)-3,6,9 nonadecatriene 
• 89353-62-8 (3E,6Z,9E)-Nonadeca-3,6,9-triene 
• 144038-11-9 1-{[2-Oxo-3-(triphenyl-λ⁵-phosphanylidene)-propyl]-phenyl-amino}-3-(triphenyl-λ⁵-phosphanylidene)-propan-2-one 
• 98291-68-0 Triphenyl-((E)-1-trimethylsilanyl-non-3-enyl)-phosphonium; bromide 
• 98291-64-6 Triphenyl-((E)-1-trimethylsilanyl-pent-3-enyl)-phosphonium; bromide 
• 98291-66-8 Triphenyl-((E)-1-trimethylsilanyl-hex-3-enyl)-phosphonium; bromide 
• 107-46-0 Hexamethyldisiloxane 
• 17615-01-9 1-(triphenyl-λ⁵-phosphanylidene)pentan-2-one 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 82294-45-9 Triphenyl-(2-phenyl-1-trimethylsilanyl-ethyl)-phosphonium; bromide 

Relevant academic research and scientific papers

Total synthesis of echinopines A and B: Exploiting a bioinspired late-stage intramolecular cyclopropanation

Total synthesis of echinopine A and B have been accomplished, based on a strategy that involved two transition-metal-mediated ene-yne cycloisomerizations. A modified Pd-catalyzed enyne cycloisomerization/ intramolecular Diels-Alder cascade rendered a more

A Novel Synthesis of 4H-Chromen-4-ones via Intramolecular Wittig Reaction

formula presented The acylphosphoranes formed in a sequential manner from the reaction of the silyl ester of O-acyl(aroyl)salicylic acids and (trimethylsilyl)-methylenetriphenylphosphorane undergo intramolecular Wittig cyclization on the ester carbonyl to afford the 4H-chromen-4-ones in good to excellent yields.

Stabilized and persistent allenylketenes

Photolyses of 2,3-bis(trimethylsilyl)-substituted methylenecyclobutenones 22-26 give essentially quantitative conversion to the allenylketenes 28-32 which have been isolated as long-lived species at room temperature. As predicted by molecular orbital calc

Phenylsilyl Chalcogenides, (Phenylsilyl)amines and Related Phosphonium (Phenylsilyl)methylides

The synthesis of 1,3-diphenyldisiloxane (1) by hydrolysis of chloro(phenyl)silane is optimized, 1,3-diphenyldisilthiane (2) is made available by the reaction of H2S with PhH2SiCl and triethylamine. 1,3-Diphenyldisilselenane (3) is prepared from K2Se and P

Synthesis and reactions of [1-(trialkylsilyl)alkylidene]triphenylphosphoranes

Alkylidenetriphenylphosphoranes 1 react with trialkyl halosilanes 2 to afford silylated alkylidenephosphoranes 5, which can be converted to acylated alkylidenephosphoranes 8 and 10 by trimethylsilyl carboxylates 6 or carboxylic anhydrides 10. Bis(acylalkylidenephosphoranes) 13-15 are available from 5 and bis(trimethylsilyl) dicarboxylates 12 or cyclic or polymeric anhydrides 16, 17.

NOUVELLE SYNTHESE DE SELS D'ALCADIEN-1,3 YL PHOSPHONIUM

A new synthetic route to alcadien-1,3 yl phosphonium salts is given.