37800-54-7

Basic information

• Product Name: Acetamide, N-(phenylmethylene)-
• CAS NO: 37800-54-7
• Molecular Formula: C9H9NO
• Molecular Weight: 147.177
• Mol File: 37800-54-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Acetamide, N-(phenylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-(phenylmethylene)-(37800-54-7)
• EPA Substance Registry System: Acetamide, N-(phenylmethylene)-(37800-54-7)

Safety Data

• Hazardous Substances Data: 37800-54-7(Hazardous Substances Data)

Upstream product

• 17599-61-0 N-benzylidene-1,1,1-trimethylsilanamine 
• 75-36-5 acetyl chloride 
• 60-35-5 acetamide 
• 100-52-7 benzaldehyde 
• 92-29-5 hydrobenzamide 

Downstream Products

• 101223-89-6 (1α,3α,4α)-2-Acetyl-1,5,6-tri-tert-butyl-3-phenyl-2-azabicyclo<2.2.0>hex-5-en-4-carbonsaeure-tert-butylester 
• 101160-42-3 (1α,3β,4α)-2-Acetyl-1,5,6-tri-tert-butyl-3-phenyl-2-azabicyclo<2.2.0>hex-5-en-4-carbonsaeure-tert-butylester 
• 101160-37-6 1,7,8-Tri-tert-butyl-3-methyl-5-phenyl-2-oxa-4-azabicyclo<4.2.0>octa-3,7-dien-6-carbonsaeure-tert-butylester 

Relevant articles and documents

A new reactivity mode for the diazo group: Diastereoselective 1,3-aminoalkylation reaction of β-amino-α-diazoesters to give triazolines

A novel mode of reactivity for the diazo group, the 1,3-addition of a nucleophile and an electrophile to the diazo group, has been realized in the intramolecular aminoalkylation of β-amino-α-diazoesters to form tetrasubstituted 1,2,3-triazolines. The reaction exhibited a broad scope, good functional group tolerance, and excellent diastereoselectivity. In addition, a new Au-catalyzed intramolecular transannulation reaction of the obtained propargyl triazolines to give pyrroles has been discovered.

A Facile Method for the Synthesis of Substituted N-Methylenecarboxamides and Alkyl N-Methylenecarbamates

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