941-44-6

Upstream product

• 143-33-9 sodium cyanide 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 75-86-5 2-hydroxy-2-methylpropanenitrile 
• 7677-24-9 trimethylsilyl cyanide 
• 151-50-8 potassium cyanide 

Downstream Products

• 7370-14-1 4-tert-butyl-1-cyanocyclohexene 
• 22434-45-3 trans-1-Piperidino-1-cyano-4-tert.butylcyclohexan 
• 22969-78-4 cis-1-Piperidino-1-cyano-4-tert.butyl-cyclohexan 
• 16499-32-4 <1-Cyan-4-tert-butyl-cyclohexyl>-dimethylamin 
• 74-90-8 hydrogen cyanide 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 130648-83-8 2-diphenylphosphino-4-t-butyl-1-cyanocyclohexane 
• 22642-99-5 1-((1S,2S,4R)-4-tert-Butyl-2-methyl-cyclohexyl)-ethanone 
• 22642-99-5 1-((1R,2S,4R)-4-tert-Butyl-2-methyl-cyclohexyl)-ethanone 
• 22173-19-9 4-tert-butyl-1-cyclohexene-1-carboxylic acid methyl ester 
• 41601-72-3 1-isopropenyl-4-t-butylcyclohexene 
• 37881-09-7 1-acetyl-4-tert-butylcyclohex-1-ene 
• 67001-73-4 4-(tert-butyl)cyclohex-1-ene-1-carboxylic acid 
• 41601-70-1 2-(4-tert-Butyl-cyclohex-1-enyl)-propan-2-ol 

Relevant academic research and scientific papers

Cu(OTf)2 catalyzed trimethylsilyl cyanide addition to carbonyl compounds

Copper (II) triflate was found to catalyze Trimethylsilyl cyanide addition to a variety of ketones and aldehydas at rt in an efficient manner.

Lanthanoid(III) Alkoxides as Novel Catalysts for a Rapid Transhydrocyanation from Acetone Cyanohydrin to Aldehydes and Ketones

A rapid transhydrocyanation from acetone cyanohydrin to several aldehydes and ketones is promoted by a catalytic amount of lanthanoid(III) alkoxide to provide the corresponding cyanohydrins.

Addition of diphenylphosphine to Michael-type olefins: the preparation of phosphine-nitrile and phosphine-ester ligands

The reactions of five Michael-type olefins with diphenylphosphine have been carried out. 1-Cyanocyclopentene, 1-cyanocyclohexene, and 4-t-butyl-1-cyanocyclohexene all provide the corresponding 2-diphenylphosphino-1-cyanocycloalkanes, and both methyl acrylate and ethyl methacrylate yield to corresponding 2-diphenylphosphinopropionates.For the products from 1-cyanocyclopentene and 1-cyanocyclohexene, 13C and 31P NMR data are consistent with the formation of both trans (Ph2P equatorial and CN axial) and cis (both Ph2P and CN equatorial) isomers.The morpholine amide of 3-diphenylphosphinopropionic acid has been obtained by treatment of methyl-3-diphenylphosphinopropionate with the dimethylaluminum adduct of morpholine.This phosphine, Ph2Pmorph, has been isolated as its palladium(II) complex, (Ph2Pmorph)2PdCl2.A phosphine-benzaldimine, Ph2P(CH2)3NC(H)C6H5, has been obtained by reacting Ph2P(CH2)3NH2, from the reduction of PhP(CH2)2CN, with benzaldehyde in the presence of molecular sieves.