37951-09-0

Basic information

• Product Name: Benzenemethanol, a-(1-methylethyl)-a-phenyl-
• CAS NO: 37951-09-0
• Molecular Formula: C16H18O
• Molecular Weight: 226.318
• Mol File: 37951-09-0.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1-methylethyl)-a-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1-methylethyl)-a-phenyl-(37951-09-0)
• EPA Substance Registry System: Benzenemethanol, a-(1-methylethyl)-a-phenyl-(37951-09-0)

Safety Data

• Hazardous Substances Data: 37951-09-0(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 2973-10-6 diisopropyl sulfate 
• 75-29-6 isopropyl chloride 
• 547-63-7 Methyl isobutyrate 
• 100-58-3 phenylmagnesium bromide 
• 611-70-1 phenyl isopropyl ketone 
• 3262-89-3 triphenylboroxine 
• 98-80-6 phenylboronic acid 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 78-84-2 isobutyraldehyde 
• 611-69-8 rac-2-methyl-1-phenylpropan-1-ol 
• 75-30-9 2-iodo-propane 
• 75-26-3 isopropyl bromide 
• 591-51-5 phenyllithium 

Downstream Products

• 119-61-9 benzophenone 
• 38660-83-2 N-(2-methyl-1-phenyl-1-propylidene) aniline 
• 145909-49-5 α-(1-methylethyl)-N-phenyl-benzenemethanamine 
• 1016565-38-0 C₁₉H₂₃NO₂S 
• 60227-39-6 1,1-diphenyl-1,2-epoxy-2-methylpropane 
• 80743-47-1 2,2-diphenyl-3-methylbutanoic acid 
• 1634-11-3 1,1-diphenyl-2-methylpropane 
• 98-82-8 Isopropylbenzene 
• 101-53-1 p-benzylphenol 
• 852058-18-5 4-Hydroxy-1-(2-methyl-1.1-diphenyl-propyl)-benzol 
• 13740-70-0 2-methyl-1,2-diphenyl-propan-1-one 
• 781-33-9 2-methyl-1,1-diphenylpropene 

Relevant articles and documents

Catalytic Functionalization of Styrenyl Epoxides via 2-Nickela(II)oxetanes

Low-valent nickel is shown to preferentially isomerize mono- or disubstituted epoxides into their corresponding aldehydes. Experiments with tetrasubstituted epoxides demonstrate that these reactions proceed via reactive 2-nickelaoxetane intermediates, and

A simple and efficient copper oxide-catalyzed Barbier-Grignard reaction of unactivated aryl or alkyl bromides with ester

An efficient one-pot route to synthesize tertiary alcohol compounds using Barbier-Grignard reaction of unactivated alkyl or aryl bromides with ester in THF at 65 C catalyzed by CuO has been developed and systematically investigated. A wide range of substituted tertiary alcohol compounds were obtained in good to high yields. The reaction is highly chemoselective. The mechanism involving the leaving group of R2O-group is discussed.

Rhodium(I)/diene-catalyzed addition reactions of arylborons with ketones

Rh(I)/diene-catalyzed addition reactions of arylboroxines/arylboronic acids with unactivated ketones to form tertiary alcohols in good to excellent yields are described. By using C2-symmetric (3aR,6aR)-3,6-diaryl-1,3a,4,6a- tetrahydropentalenes as ligands, the asymmetric version of such an addition reaction, with up to 68% ee, was also realized.