37985-11-8

Basic information

• Product Name: 1-methyl-4-(4-phenyl-1,3-butadienyl)benzene
• Synonyms: 1-methyl-4-(4-phenyl-1,3-butadienyl)benzene
• CAS NO: 37985-11-8
• Molecular Formula: C₁₇H₁₆
• Molecular Weight: 220.30894
• Mol File: 37985-11-8.mol
• Article Data: 14

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-methyl-4-(4-phenyl-1,3-butadienyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-4-(4-phenyl-1,3-butadienyl)benzene(37985-11-8)
• EPA Substance Registry System: 1-methyl-4-(4-phenyl-1,3-butadienyl)benzene(37985-11-8)

Safety Data

• Hazardous Substances Data: 37985-11-8(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 622-47-9 4-tolylacetic acid 
• 2378-86-1 4-methylbenzyltriphenylphosphonium bromide 
• 104-82-5 4-Methylbenzyl chloride 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 52147-97-4 trans 2-phenylethenesulfonyl chloride 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 180906-68-7 (E,E)-4-phenyl-1-(4-methylphenylseleno)-1,3-butadiene 
• 100-34-5 benzene diazonium chloride 
• 104-87-0 4-methyl-benzaldehyde 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 696-61-7 4-tolylmagnesium chloride 
• 104-81-4 4-Methylbenzyl bromide 
• 28010-12-0 5-phenylpenta-2,4-dienoic acid 

Downstream Products

• 102478-08-0 cis-2-tolyl-5-phenyl-8-oxabicyclo<4.3.0>non-3-ene-7,9-dione 
• 19723-03-6 7-methyl-1-phenylnaphthalene 
• 27331-34-6 1-(4-methylphenyl)naphthalene 
• 29304-62-9 6-methyl-4-phenyl-1,2-dihydro-naphthalene 
• 6936-14-7 1,2-dihydro-4-(4-methylphenyl)naphthalene 
• 37985-00-5 trans-1-(p-Tolyl)-4-phenylbut-2-en 
• 52010-91-0 4-((1E,3E)-4-phenylbuta-1,3-dienyl)benzaldehyde 

Relevant articles and documents

A NOVEL SYNTHESIS OF (E,E)-1,4-DIARYL-1,3-BUTADIENES BY THE RUTHENIUM(II) CATALYZED REACTION OF (E)-2-ARYLETHENESULFONYL CHLORIDES WITH VINYLARENES

Symmetrical and unsymmetrical (E,E)-1,4-diaryl-1,3-butadienes can be prepared in high yields from (E)-2-arylethenesulfonyl chlorides by treating with vinylarenes in the presence of ruthenium(II) phosphine complex in benzene.

Synthesis of stilbene derivatives via visible-light-induced cross-coupling of aryl diazonium salts with nitroalkenes using-NO2 as a leaving group

The straightforward visible-light-induced synthesis of stilbene compounds via the cross-coupling of nitroalkenes and diazonium tetrafluoroborates under transition-metal-free conditions is described. The protocol uses green LEDs as light sources and eosin Y as an organophotoredox catalyst. Broad substrate scope and exclusive selectivity for the (E)-configuration of stilbenes are observed. This protocol proceeds via a radical pathway, with nitroalkenes serving as the radical acceptor, and the nitro group is cleaved during the process.

Synthesis of 1,4-diarylbuta-1,3-dienes through palladium-catalyzed decarboxylative coupling of unsaturated carboxylic acids

It has been found that readily available hydroxylated cinnamic acids such as ferulic acid undergo palladium-catalyzed decarboxylative coupling with aryl iodides and internal alkynes in a 1:1:1 manner to produce 1,4-diarylbuta-1,3- dienes. The butadiene synthesis has also been achieved through the coupling of aryl halides with dienoic acids. Some of the products exhibit solid-state fluorescence.