380-34-7Relevant articles and documents
Synthesis and use of partially fluorinated dialkyl ethers derived from hexafluoropropylene
Il'in,Bakhmutov,Ivanova,Furin,Tolstikova,Sukhinin
, p. 98 - 101 (2004)
A procedure was developed for preparing partially fluorinated dialkyl ethers by the reaction of hexafluoropropylene with aliphatic and polyfluorinated alcohols in the presence of KOH. On treatment with concentrated sulfuric acid, these ethers form alkyl esters of acids, and on treatment with KOH, alkenyl ethers.
Method for removing unsaturated impurities in 1, 1, 2, 3, 3 and 3 - hexafluoropropyl hydrofluoroether crude product
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Paragraph 0057-0064, (2021/10/27)
The invention provides a method of removing 1. [] The hydrofluoroether impurities, pentafluoropropylene hydrofluoroether, and, 1 1 pentafluoropropylene 2 hydrofluoroether 3 impurities 3 can 3 - be well separated to provide, hexafluoropropyl hydrofluoroether product 1 having a 1 2 purity of 3 3 - at least. 1 2 1, 2, 3, 3, 3 - 3 1 1 3 3 - 99% 3 3 - 2 3The method does not use dangerous chemical, greatly improves the operation safety, does not generate waste harmful to the environment, and can be regenerated and reused by the adsorbent silica gel column. Cost is reduced, and resources are saved.
Palladium(0)-catalyzed hydroalkoxylation of hexafluoropropene: Synthesis of hydrofluoroethers under neutral conditions
Matsukawa, Yasuhisa,Mizukado, Junji,Quan, Heng-Dao,Tamara, Masanori,Sekiya, Akira
, p. 1128 - 1130 (2007/10/03)
No vinyl ether by-products are formed in the palladium(0)-complex catalyzed hydroalkoxylation of hexafluoropropene (see scheme). Saturated hydrofluoro-ethers are selectively synthesized with alcohols or phenols under neutral conditions in the presence of