3815-24-5

Basic information

• Product Name: N,N-Dimethylnaphthalene-1-carboxamide
• Synonyms: N,N-Dimethyl-1-naphthalenecarboxamide;N,N-Dimethylnaphthalene-1-carboxamide
• CAS NO: 3815-24-5
• Molecular Formula: C₁₃H₁₃NO
• Molecular Weight: 0
• Mol File: 3815-24-5.mol
• Article Data: 28

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N,N-Dimethylnaphthalene-1-carboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-Dimethylnaphthalene-1-carboxamide(3815-24-5)
• EPA Substance Registry System: N,N-Dimethylnaphthalene-1-carboxamide(3815-24-5)

Safety Data

• Hazardous Substances Data: 3815-24-5(Hazardous Substances Data)

Upstream product

• 18503-89-4 N,N-dimethylformamide diisopropyl acetal 
• 90-11-9 1-Bromonaphthalene 
• 86-55-5 1-naphthalenecarboxylic acid 
• 506-59-2 N,N-dimethylammonium chloride 
• 68-12-2 N,N-dimethyl-formamide 
• 90-12-0 1-Methylnaphthalene 
• 118-31-0 (naphth-1-yl)methylamine 
• 127-19-5 N,N-dimethyl acetamide 
• 4780-79-4 1-naphthalene methanol 
• 67-56-1 methanol 
• 66-77-3 1-naphthaldehyde 
• 124-40-3 dimethyl amine 
• 32488-43-0 N,N-dimethylform-¹³C-amide 
• 42930-04-1 tert-butyl dimethylcarbamoperoxoate 

Downstream Products

• 4780-79-4 1-naphthalene methanol 
• 16413-71-1 N,N-dimethyl(naphthalen-1-yl)methanamine 
• 1472062-95-5 2-chloro-4-(1-naphthalene-yl)-6-phenyl-1,3,5-triazine 
• 560091-45-4 N-(pyrimidin-2-yl)-1-naphthamide 
• 86-53-3 1-Cyanonaphthalene 
• 86-55-5 1-naphthalenecarboxylic acid 
• 124-40-3 dimethyl amine 
• 77144-27-5 1-(Cyclopenta-2,4-dienylidene-phenyl-methyl)-naphthalene 
• 66-77-3 1-naphthaldehyde 

Relevant articles and documents

Electrochemical, ESR and quantum chemical study of 1-substituted naphthalenes and their radical anions

Electrochemical reduction and oxidation of a series of 1-substituted naphthalenes (1-X-naphthalenes) have been studied by the method of cyclic voltammetry (CV). The first reduction peak of the majority of these compounds corresponds to a one-electron transfer to form the relatively stable radical anion (RA). For these species, ESR spectra have been registered and interpreted, the life time has been estimated. The first oxidation peaks of 1-X-naphthalenes are irreversible and correspond to a transfer of two or more electrons. Copyright

Palladium-Catalyzed N-Acylation of Tertiary Amines by Carboxylic Acids: A Method for the Synthesis of Amides

A palladium-catalyzed N-acylation of tertiary amines by carboxylic acids was achieved through C-N cleavage. This reaction showed a wide substrate scope. Both aromatic and aliphatic acids served well as the acylating reagents and coupled with tertiary amines to produce the corresponding amides in good to excellent yields. With the strategy, bioactive carboxylic acids were also efficiently modified, highlighting the synthetic value of the process in organic synthesis.

Palladium-catalyzed directing group-assisted C8-triflation of naphthalenes

The transition-metal-catalyzed direct triflation of naphthyl amides and naphthyl ketones has been accomplished for the first time. Benzophenone (BP) was found to be a suitable ligand for the cross-coupling reactions. Density functional theory (DFT) calculations revealed that excessive amounts of HOTf inhibit the reductive elimination of the C-F bond to realize the unusual reductive elimination of the C-OTf bond.