38164-55-5Relevant academic research and scientific papers
Synthesis of enantiomerically enriched 3-amino-2-oxindoles through a palladium-mediated asymmetric intramolecular arylation of α-ketimino amides
Tolstoy, Paeivi,Lee, Samantha X. Y.,Sparr, Christof,Ley, Steven V.
, p. 4810 - 4813,4 (2012/12/12)
A highly efficient and enantioselective synthesis of 3-amino-2-oxindoles through a palladium-catalyzed asymmetric intramolecular arylation of R-ketimino amides using (R)-DiFluorPhos as the coordinating ligand is reported. This report constitutes the first
Synthesis of enantiomerically enriched 3-amino-2-oxindoles through a palladium-mediated asymmetric intramolecular arylation of α-ketimino amides
Tolstoy, P?ivi,Lee, Samantha X.Y.,Sparr, Christof,Ley, Steven V.
, p. 4810 - 4813 (2013/01/15)
A highly efficient and enantioselective synthesis of 3-amino-2-oxindoles through a palladium-catalyzed asymmetric intramolecular arylation of R-ketimino amides using (R)-DiFluorPhos as the coordinating ligand is reported. This report constitutes the first
A facile pathway to enantiomerically enriched 3-hydroxy-2-oxindoles: Asymmetric intramolecular arylation of α-keto amides catalyzed by a palladium-DifluorPhos complex
Yin, Liang,Kanai, Motomu,Shibasaki, Masakatsu
, p. 7620 - 7623 (2011/09/30)
Less metal wastes: The first catalytic, enantioselective intramolecular aryl-transfer reaction of aryl triflates to ketones has been developed (see scheme; R1=R2=aromatic and aliphatic). This method features overall practicality, inc
Potassium organotrifluoroborates: New partners in palladium-catalysed cross-coupling reactions
Darses, Sylvain,Michaud, Guillaume,Genet, Jean-Pierre
, p. 1875 - 1883 (2007/10/03)
The preparation of various potassium organotrifluoroborates bearing either aryl, alkenyl, or alkynyl substituents is described. These stable salts are shown to be very efficient partners in palladium-catalysed cross- coupling reactions with arenediazonium salts, affording biaryl and styrene derivatives in high yields.
Palladium-catalyzed cross-coupling reactions of arenediazonium tetrafluoroborates with aryl- And alkeriylboronic acids
Darses, Sylvain,Jeffery, Tuyet,Jean-Louis,Demoute, Jean-Pierre,Genet, Jean-Pierre
, p. 1095 - 1102 (2007/10/03)
Arcnediazonium tetrafluoroborates undergo a facile and efficient palladium-catalyzed cross-coupling reaction with aryl- and alkenylboronic acids at ambient temperature, without addition of base. The reaction described is characterized by a high chemoselectivity because bromide and trifiate functional groups are tolerated. Eisevier,.
