38328-19-7

Upstream product

• 3923-51-1 1,1-diphenylprop-2-en-1-ol 
• 1730-25-2 allylmagnesium bromide 
• 556-56-9 allyl iodid 
• 4801-15-4 3-bromo-1,1-diphenyl-1-propene 
• 119-61-9 benzophenone 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 26189-62-8 phenyl 2,2-diphenylethenyl sulfone 
• 7051-34-5 cyclopropylcarbinyl bromide 

Downstream Products

• 207455-92-3 1,1-diphenylhex-5-en-2-ol 
• 7714-72-9 6,6-diphenylfulvene 
• 1351520-88-1 6-deuterio-1,1-diphenyl-1-hexene 
• 119-61-9 benzophenone 
• 2100-17-6 4-pentenal 

Relevant academic research and scientific papers

Alkenylation of unactivated alkyl bromides through visible light photocatalysis

Two visible-light driven alkenylation reactions of unactivated alkyl bromides, which were enabled by the use of Ir(dF(CF3)ppy)2(dtbbpy)PF6 as the photocatalyst and (TMS)3SiH as the atom transfer reagent to activate the alkyl bromides, were described for the first time. These protocols can be used to produce a variety of alkenes from easily available feedstock with good reaction efficiency and high chemoselectivity under mild reaction conditions. To further demonstrate the applicability of the present strategy, the alkenylation of bioactive molecules and glycosyl bromides, as well as the alkynylation of unactivated alkyl bromides, was proven to be feasible.

Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates

We developed catalytic intermolecular C(sp3)-C(sp3) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.

Selective Alkylation and Allylation of Allylic Halides by Tetraorganoidates: Regio- and Stereo-selective Synthesis of Rosefuran and Sesquirosefuran

Tetraalkylindanes regioselectively alkylate allylic bromides at the α-carbon.In this way, 1,5-dienes have been regio- and stereo-selectively synthesized by the allyl-allyl coupling of allylic bromides and allylic indates, including rosefuran 1 and sequirosefuran 3.