3839-89-2

Upstream product

• 222851-56-1 N-phenylsulfinylamine 
• 62-53-3 aniline 
• 2713-47-5 S,S-difluoro-N-phenyl-sulfimide 
• 2325-27-1 N-phenyltriphenyliminophosphorane 
• 3768-55-6 N-trimethylsilylaniline 
• 996-37-2 1,1,1-trimethyl-N,N-bis(trimethylsilyl)stannanamine 
• 4039-32-1 lithium hexamethyldisilazane 
• 700-16-3 Pentafluoropyridine 
• 136123-48-3 C₁₃H₈F₁₃NOS 

Downstream Products

• 32119-42-9 N-phenylcyclohex-1-enecarboxamide 
• 62208-49-5 4-benzhydrylidene-3,5-diphenyl-1,3,4,5-tetrahydro-benzo[1,2,4,7]thiatriazepine 
• 1519-73-9 N-phenylimine of bis(trifluoromethyl)ketene 
• 36138-87-1 2-Phenyl-cis-2-butenanilid 
• 36138-85-9 2-phenyl-but-2-enoic acid N-anilinosulfanyl-anilide 
• 42093-13-0 2,3-Dihydro-3-oxo-2,5-diphenyl-1,2,4-thiadiazole 
• 62002-23-7 2,5-diphenyl-[1,3,2,4]dithiadiazole 
• 62002-25-9 5-(4-chloro-phenyl)-2-phenyl-[1,3,2,4]dithiadiazole 
• 62002-28-2 5-(4-chloro-phenyl)-2-phenyl-[1,2,4]thiadiazol-3-one 
• 62002-24-8 5-(4-methoxy-phenyl)-2-phenyl-[1,3,2,4]dithiadiazole 
• 62002-26-0 5-(4-methoxy-phenyl)-2-phenyl-[1,2,4]thiadiazol-3-one 
• 29376-74-7 2,4,4,5-tetraphenyl-[1,2,5]thiadiazolidin-3-one 
• 22294-25-3 2,4,4-triphenyl-1-phenylimino-1λ⁴-[1,2]thiazetidin-3-one 
• 36146-93-7 2-benzhydrylidene-3,5,7,7-tetraphenyl-[1,4,3,5]oxathiadiazepan-6-one 

Relevant academic research and scientific papers

Rapid and effective synthesis of diarylsulfur diimides from substituted anilines and sulfur monochloride

A one-pot and effective procedure has been developed for the synthesis of symmetrical diarylsulfur diimides from anilines, sulfur monochloride, and DABCO in good yields (70-90%). A plausible mechanism for this transformation has been proposed. Georg Thiem

Reactions of arylthiazylamides with internal and external fluoro electrophiles - Formation of products with unusual structures

The heteroatom reactivity of the title anions [as (Me2N)3S+ and Cs+ salts] toward both internal and external fluoro electrophiles has been investigated. The intramolecular nucleophilic cyclization of [ArNSN]- (as the cesium salts) bearing at least one ortho fluorine afforded 2,1,3-benzothiadiazoles (e.g. 2a,b), whereas intermolecular condensation with polyfluorinated pyridine and naphthalene afforded Ar-N=S=N-R with R = 4-PyF (4) and R = 2-NpF (8). Further interaction of [ArNSN]- with 4 or 8 proceeded with the transfer of NSN units resulting in (ArN=)2S (5) and [RNSN]-, followed by decomposition (R = 4-PyF) to 4-PyFNH2 (6) or intramolecular cyclization (R = 2-NpF) to the polyfluorinated thiadiazole 9. The compounds of types 4, 5, 8, and 9 have been characterized by single-crystal X-ray diffraction as having both Z,E and Z,Z configurations [8 and 9 as molecular complexes with C10F8 and (Ph-N=)2S (5e), respectively, featuring π-stacking interactions of the arene-polyfluoroarene type]. Besides normal aryl-polyfluoroaryl interactions, the 8·C10F8 complex also displays unusual polyfluoroaryl-polyfluoroaryl π-stacking.

REACTIONS OF α,α,ω-TRIHYDROPOLYFLUOROALKOXYTRIFLUOROSULFURANES WITH PRIMARY AMINES AND AMIDES

α,α,ω-Trihydropolyfluoroalkoxytrifluorosulfuranes react with primary amides or their N,N'-di(trimethylsilyl) derivatives to form acid fluoride derivatives of N-substituted polyfluoroalkyliminosulfurous acids.The thermal stability of these products depends

Skeletal scrambling of sulphur diimide radical anions

In the presence of a catalytic quantity of alkali metal mixtures of sulphur diimides RNSNR and R'NSNR' (R, R' = Ph, 4-C6H4Me, 4-C6H4OMe, SiMe3, SPh) undergo a rapid scrambling of the R and R' groups.When R and R' are significantly different (e.g., R = Ph,

SOME KINETIC ASPECTS OF THE ALCOHOLYSIS OF N,N'-DIARYLSULPHURDIIMIDES

Kinetic determinations (at 22 deg C) show that the ethanolysis of N,N'-diarylsulphurdiimides 1 - 9, catalysed by anhydrous copper(II) chloride, obeys a first-order rate law with respect to N,N'-diarylsulphurdiimide.The logarithm of the observed first-order rate constants (at the same concentration of the catalyst) can be correlated with the Hammett ? substituent constants.The ethanolysis rate of 1 - 9 is increased by the electron-withdrawing effect of the substituents linked to the aromatic rings of N,N'-diarylsulphurdiimide.The observed first-order rate constant of the CuCl2-catalysed ethanolysis of N,N'-bis(p-tolyl)sulphurdiimide, 3, is directly proportional to the catalyst concentration: kobs = k2.The second-order rate constants, k2, of the alcoholysis of 3 were measured in four alcohols different from ethanol.These constants seem to be a function of the polarity of the reaction medium and of the steric hindrance of the alcohol.Finally, it was ascertained that the catalysing power of CuCl2 in the ethanolysis of 3 is higher than that of NiCl2 and CoCl2.