38513-22-3Relevant academic research and scientific papers
A facile regio- and stereocontrolled synthesis of (E)-disubstituted vinyl sulfones via transformation of alkenylzirconocenes with sulfonyl chlorides
Duan, De-Hui,Huang, Xian
, p. 317 - 318 (1999)
Alkenylzirconium reagents, readily obtained by hydrozirconation of terminal alkynes, can smoothly react with sulfonyl chlorides to afford (E)- disubstituted vinyl sulfones in moderate to good yields. Some γ- functionalized vinyl sulfones can be also conve
Sulfones as chemical chameleons. Heteroatom substituted allyl sulfones as conjugative reagents
Trost, B. M.,Ghadiri, M. Reza
, p. 433 - 442 (2007/10/02)
3-Phenylthio-1-phenylsulfonylprop-2-ene, Z-3-methoxy-, and Z-3-benzyloxy-1-phenylsulfonylprop-2-ene serve as valuable building blocks wherein the sulfone imparts both nucleophilic and electrophilic properties to the allyl moiety.Alkylations of the corresp
