3852-14-0Relevant articles and documents
Photochemistry of Aliphatic Dipeptides in Aqueous Solution
Birch, David,Coyle, John D.,Hill, Roger R.,Jeffs, Graham E.,Randall, David
, p. 796 - 797 (1984)
U.v. irradiation of aqueous solutions of glycylglycine or alanylglycine in the absence of oxygen leads to quantitative N-terminal deamination, and the formation of acetamide or propionamide, respectively, in high chemical yield.
Photochemistry of dipeptides in aqueous solution
Hill, Roger R.,Coyle, John D.,Birch, David,Dawe, Edwin,Jeffs, Graham E.,Randall, David,Stec, Iwan,Stevenson, Tessa M.
, p. 1805 - 1817 (2007/10/02)
The photochemical lability of peptides is poorly understood, largely because of the lack of product data. In the present study, product analyses have been carried out following the photolyses in aqueous solution of selected glycyl dipeptides (Gly-Gly, DL-Ala-Gly, L-Val-Gly, L-Pro-Gly, L-Phe-Gly, and Gly-L-Phe), L-prolyl-L-phenylalanine, and L-phenylalanyl-L-proline. Efficient deamination and decarboxylation of aliphatic dipeptides generate thermal precursors of simple amides in a photoinduced electron-transfer process involving the peptide bond. An analogous pathway in the photodegradation of phenylalanyl peptides suffers competition from other types of reaction.
DEDISILOXANATION REACTION (ELIMINATION OF DISILOXANE) IN THE REACTIONS OF N-(SILOXYMETHYL) DERIVATIVES OF AMINES AND AMIDES WITH CHLORO-, (ACYLOXY)-, AND AMINO-SILANES
Kozyukov, V. P.,Kozyukov, Vik. P.,Mironov, V. F.
, p. 100 - 106 (2007/10/02)
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