38574-62-8

Basic information

• Product Name: methyl (S)-(+)-2-benzylpropionate
• Synonyms: methyl (S)-(+)-2-benzylpropionate
• CAS NO: 38574-62-8
• Molecular Weight: 178.231
• Mol File: 38574-62-8.mol
• Article Data: 75

Chemical Properties

• CAS DataBase Reference: methyl (S)-(+)-2-benzylpropionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (S)-(+)-2-benzylpropionate(38574-62-8)
• EPA Substance Registry System: methyl (S)-(+)-2-benzylpropionate(38574-62-8)

Safety Data

• Hazardous Substances Data: 38574-62-8(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 300-57-2 allylbenzene 
• 201230-82-2 carbon monoxide 
• 1007-32-5 benzyl ethyl ketone 
• 84782-16-1 methyl 3-bromo-2-methyl-2-phenylpropanoate 
• 186581-53-3 diazomethane 
• 109-72-8 n-butyllithium 
• 501-52-0 3-Phenylpropionic acid 
• 74-88-4 methyl iodide 
• 909413-25-8 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine 
• 80-62-6 methacrylic acid methyl ester 
• 591-50-4 iodobenzene 
• 753016-42-1 ((S)-1-Methoxy-2-methyl-cyclopropoxy)-trimethyl-silane 
• 155956-28-8 (2'S,5R)-1-(1'-oxo-2'-phenylmethylpropyl)-3,3,5-trimethylpyrrolidin-2-one 

Downstream Products

• 14367-67-0 2-methyl-3-phenylpropionic acid 
• 29393-16-6 methyl (2R)-2-methyl-3-phenylpropanoate 
• 123820-51-9 ((Z)-1-Methoxy-2-methyl-3-phenyl-propenyloxy)-trimethyl-silane 
• 114984-80-4 2-benzyl-1,1-diphenylprop-1-ene 
• 7499-19-6 (S)-2-phenylmethylpropanamide 

Relevant articles and documents

The unexpected kinetic effect of enzyme mixture: The case of enzymatic esterification

During the studies towards synthesis of carboxylic acids esters, using ethyl carbonate and carboxylic acid as substrates, we found that different single enzyme systems provide model ethyl 3-phenylpropanoate in very low yield. Systematic studies proved tha

C?Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3-Enynes

A new family of carbon-bound boron enolates, generated by a kinetically controlled halogen exchange between chlorocatecholborane and silylketene acetals, is described. These C?boron enolates are demonstrated to activate 1,3-enyne substrates in the presence of a Pd0/Senphos ligand complex, resulting in the first examples of a carboboration reaction of an alkyne with enolate-equivalent nucleophiles. Highly substituted dienyl boron building blocks are produced in excellent site-, regio-, and diastereoselectivity by the described catalytic cis-carboboration reaction.

A general platinum-catalyzed alkoxycarbonylation of olefins

Hydroxy- and alkoxycarbonylation reactions constitute important industrial processes in homogeneous catalysis. Nowadays, palladium complexes constitute state-of-the-art catalysts for these transformations. Herein, we report the first efficient platinum-catalysed alkoxycarbonylations of olefins including sterically hindered and functionalized ones. This atom-efficient catalytic transformation provides straightforward access to a variety of valuable esters in good to excellent yields and often with high selectivities. In kinetic experiments the activities of Pd- and Pt-based catalysts were compared. Even at low catalyst loading, Pt shows high catalytic activity.