909413-25-8

Basic information

• Product Name: 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine
• Synonyms: 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine
• CAS NO: 909413-25-8
• Molecular Weight: 450.227
• Mol File: 909413-25-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine(909413-25-8)
• EPA Substance Registry System: 6-(tert-butyl)-12-phenyl-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine(909413-25-8)

Safety Data

• Hazardous Substances Data: 909413-25-8(Hazardous Substances Data)

Upstream product

• 194285-51-3 N,N -bis(2-bromobenzyl)-2-methylpropan-2-amine 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 1070804-80-6 6-(tert-butyl)-12-chloro-5,6,7,12-tetrahydrodibenzo[c,f][1,5]azastibocine 
• 98-80-6 phenylboronic acid 

Downstream Products

• 1885-38-7 cinnamic nitrile 
• 621-79-4 cinnamamide 
• 22946-43-6 (E)-methyl-2-methyl-3-phenylacrylate 
• 2757-04-2 phenyl cinnamate 
• 14990-09-1 tert-butyl cinnamate 
• 103-36-6 ethyl 3-phenyl-2-propenoate 
• 62839-71-8 (E)-1-phenyl-1-decene 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 29478-39-5 (E)-1-phenyloct-1-en-3-one 
• 1896-62-4 (E)-benzalacetone 
• 3152-68-9 (1E)-1-phenylpent-1-en-3-one 
• 29393-16-6 methyl 2-methyl-3-phenylpropionate 
• 20795-51-1 1-phenylpentan-3-one 
• 120609-18-9 (+/-)-5-methyl-4-phenylhexan-2-one 

Relevant articles and documents

Nickel- and Palladium-Catalyzed Cross-Coupling Reactions of Organostibines with Organoboronic Acids

A strategy for the formation of antimony-carbon bond was developed by nickel-catalyzed cross-coupling of halostibines. This method has been applied to the synthesis of various triaryl- and diarylalkylstibines from the corresponding cyclic and acyclic halostibines. This protocol showed a wide substrate scope (72 examples) and was compatible to a wide range of functional groups such as aldehyde, ketone, alkene, alkyne, haloarenes (F, Cl, Br, I), and heteroarenes. A successful synthesis of arylated stibine 3 a in a scale of 34.77 g demonstrates high synthetic potential of this transformation. The formed stibines (R3Sb) were then used for the palladium-catalyzed carbon–carbon bond forming reaction with aryl boronic acids [R?B(OH)2], giving biaryls with high selectivity, even the structures of two organomoieties (R and R′) are very similar. Plausible catalytic pathways were proposed based on control experiments.