386253-22-1Relevant academic research and scientific papers
Total synthesis of (+)-lepadin B: Stereoselective synthesis of nonracemic polysubstituted hydroquinolines using an RC-ROM process
Barbe, Guillaume,Charette, Andre B.
supporting information; experimental part, p. 13873 - 13875 (2009/02/06)
This communication describes a new tandem metathesis reaction for which an RC-ROM mechanism was experimentally supported. This process was successfully applied to the synthesis of cis-fused polyhydroquinolines enabling a short stereoselective total synthe
Silver ion-induced grob fragmentation of γ-amino iodides: Highly stereoselective synthesis of polysubstituted piperidines
Barbe, Guillaume,St-Onge, Miguel,Charette, Andre B.
supporting information; experimental part, p. 5497 - 5499 (2009/06/18)
(Chemical Equation Presented) A new concerted silver ion-mediated Grob fragmentation process is described in which a 1,2-dihydropyridinium ion is formed and trapped in situ with Grignard reagents in a highly regio- and diastereoselective fashion. Using th
