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Silane, trimethyl[(4-methyl-1-cyclohexen-1-yl)oxy]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 38671-78-2 Structure
  • Basic information

    1. Product Name: Silane, trimethyl[(4-methyl-1-cyclohexen-1-yl)oxy]-
    2. Synonyms:
    3. CAS NO:38671-78-2
    4. Molecular Formula: C10H20OSi
    5. Molecular Weight: 184.354
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 38671-78-2.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Silane, trimethyl[(4-methyl-1-cyclohexen-1-yl)oxy]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Silane, trimethyl[(4-methyl-1-cyclohexen-1-yl)oxy]-(38671-78-2)
    11. EPA Substance Registry System: Silane, trimethyl[(4-methyl-1-cyclohexen-1-yl)oxy]-(38671-78-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 38671-78-2(Hazardous Substances Data)

38671-78-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 38671-78-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,6,7 and 1 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 38671-78:
(7*3)+(6*8)+(5*6)+(4*7)+(3*1)+(2*7)+(1*8)=152
152 % 10 = 2
So 38671-78-2 is a valid CAS Registry Number.

38671-78-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name trimethyl-(4-methylcyclohexen-1-yl)oxysilane

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:38671-78-2 SDS

38671-78-2Relevant articles and documents

HMOX1 inducers

-

Page/Page column 35, (2020/09/18)

The present invention is related to compounds of structure (I) as heme oxygenase 1 (HMOX 1) inducers. The present invention is also related a method of controlling the activity or the amount, or both the activity and the amount, of heme-oxygenase 1 in a mammalian subject. The definitions of the variables are provided herein.

Palladium-Mediated Remote Functionalization in γ- And ?-Arylations and Alkenylations of Unblocked Cyclic Enones

Saini, Gaurav,Mondal, Arpan,Kapur, Manmohan

supporting information, p. 9071 - 9075 (2019/11/14)

We report herein an extensive investigation of simple and regioselective endo- as well as exo-γ-arylations of silyl-dienol ethers of unblocked cyclic enones with the utilization of palladium-catalyzed, modified Kuwajima-Urabe conditions. We have also successfully explored a new exo-?-arylation of silyl-trienol ethers of π-extended cyclic enones. In addition, we also report, herein, exclusive γ- and ?-alkenylation of silyl-dienol and silyl-trienol ethers of cyclic enones.

A Solvent-Free Reaction for Silyl Enol Ethers Synthesis

Morozzi, Chiara,Rosati, Ornelio,Curini, Massimo,Lanari, Daniela

supporting information, p. 126 - 130 (2017/12/28)

Silyl enol ethers are extremely useful nucleophilic intermediates for chemical transformations because they are synthetically versatile substrates for a wide range of C-C bond-forming reactions. Here, we present a new, mild, and solvent-free procedure for the synthesis of silyl enol ethers that employs a catalytic amount of solid-supported base and an equimolar amount of N, O -(bistrimethylsilyl)acetamide as a silylating agent.

The cinchona primary amine-catalyzed asymmetric epoxidation and hydroperoxidation of α,β-unsaturated carbonyl compounds with hydrogen peroxide

Lifchits, Olga,Mahlau, Manuel,Reisinger, Corinna M.,Lee, Anna,Fares, Christophe,Polyak, Iakov,Gopakumar, Gopinadhanpillai,Thiel, Walter,List, Benjamin

supporting information, p. 6677 - 6693 (2013/06/05)

Using cinchona alkaloid-derived primary amines as catalysts and aqueous hydrogen peroxide as the oxidant, we have developed highly enantioselective Weitz-Scheffer-type epoxidation and hydroperoxidation reactions of α,β-unsaturated carbonyl compounds (up to 99.5:0.5 er). In this article, we present our full studies on this family of reactions, employing acyclic enones, 5-15-membered cyclic enones, and α-branched enals as substrates. In addition to an expanded scope, synthetic applications of the products are presented. We also report detailed mechanistic investigations of the catalytic intermediates, structure-activity relationships of the cinchona amine catalyst, and rationalization of the absolute stereoselectivity by NMR spectroscopic studies and DFT calculations.

Di-tert-butylmagnesium as an atom-efficient, carbon-centred base reagent for the preparation of silyl enol ethers from ketones

Kerr, William J.,Watson, Allan J. B.,Hayes, Douglas

experimental part, p. 1386 - 1390 (2009/04/06)

Di-tert-butylmagnesium has been found to be a reactive, yet non-nucleophilic and non-reductive, carbon-centred base for the deprotonation of a series of ketones. This reagent demonstrates equally high reactivity when used as either the pre-formed reagent, or in a more accessible one-pot protocol from the parent Grignard reagent, and offers improved atom-efficiency over more traditionally employed bases. Georg Thieme Verlag Stuttgart.

Preventive and/or Therapeutic Agent for Diabetic Vascular Disorder and Respiratory Disorder

-

, (2009/01/24)

The present invention provides preventive and/or therapeutic agents for either one, or both, of a diabetic vascular disorder and a diabetic respiratory disorder comprising, as an active ingredient, a cyclohexenone long chain alcohol compound represented b

Synthesis of 1,2,3,4-tetrahydrocarbazoles and related tricyclic indoles

Scott, Tricia L.,Burke, Nicholas,Carrero-Martínez, Grissell,S?derberg, Bj?rn C.G.

, p. 1183 - 1190 (2007/10/03)

Reduction of 2-(2-nitrophenyl)-2-cyclohexene-1-ones using palladium on carbon under 1 atm of hydrogen gas at ambient temperature affords 1,2,3,4-tetrahydrocarbazoles in excellent isolated yields. The starting materials were prepared by intermolecular Stille coupling of 2-iodo-2-cyclohexen-1-ones with 2-(tributylstannyl)-1-nitrobenzenes.

Bismesitylmagnesium: A thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers

Kerr, William J.,Watson, Allan J. B.,Hayes, Douglas

, p. 5049 - 5051 (2008/09/17)

Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures. The Royal Society of Chemistry.

Synthesis of 5-substituted 4,5,6,7-tetrahydroindoles from cyclohexanones

Lee, Chang Kiu,Lee, In-Sook Han,Noland, Wayland

, p. 419 - 428 (2008/02/09)

5-Substituted 4,5,6,7-tetrahydroindoles were prepared from 4-substituted cyclohexanones in three steps: conversion to an enol silyl ether, introduction of a formylmethyl group at 2-C, and the Paal-Knorr pyrrole synthesis by reacting the 1,4-dicarbonyl compounds with ammonia. The substituents are H, methyl, ethyl, tert-butyl, methoxy, and phenyl.

THERAPEUTIC AGENT FOR SENSORY ABNORMALITY

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Page/Page column 13, (2008/06/13)

The present invention provides therapeutic agents for sensory disorders represented by the following formula (1): [wherein R1, R2, and R3 each represent a hydrogen atom or a methyl group, and X represents a linear or branc

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