3891-47-2Relevant academic research and scientific papers
Reactions of Carbohydrate Acetals with Organolithium Compounds. - Synthesis of 3-Deoxy-α-D-erythro-hexofuranosid-2-ulose and 6-Deoxy-α-D-xylo-hexofuranos-5-ulose
Beermann, Heinrich,Jung, Guenter,Klemer, Almuth
, p. 1543 - 1547 (2007/10/02)
Methyl 2,3:5,6-di-O-isopropylidene-α-D-mannofuranoside (1) reacts with lithium diisopropylamide to give the methyl 3-deoxy-5,6-O-isopropylidene-α-D-erythro-hexofuranosid-2-ulose (2), while 1,2-O-isopropylidene-3,5,6-O-methylidyne-α-D-glucofuranose (3) yields 6-deoxy-1,2-O-isopropylidene-α-D-xylo-hexofuranos-5-ulose (4).
