39000-58-3Relevant academic research and scientific papers
Enantioselective hydride abstraction in organic substrates: A novel use for chiral carbenium ions
Magdziak, Derek,Pettus, Liping H.,Pettus, Thomas R. R.
, p. 557 - 559 (2001)
(Matrix presented) It is surprising that chiral cations have not been used to distinguish between prochiral hydrides when converse notions, such as asymmetric addition of a hyride to a prochiral functional group or use of a chiral anion to distinguish bet
Ammonia-free Birch reductions with sodium stabilized in silica gel, Na-SG(I)
Costanzo, Michael J.,Patel, Mitul N.,Petersen, Kathryn A.,Vogt, Paul F.
supporting information; experimental part, p. 5463 - 5466 (2010/01/11)
Ammonia-free Birch reduction conditions were developed based upon sodium stabilized in silica gel for a variety of substrates. In general, the yields were similar to those reported for lump sodium in liquid ammonia.
