3920-79-4Relevant articles and documents
Mono-Heteroatom Substitution for Harnessing Excited-State Structural Planarization of Dihydrodibenzo[a,c]phenazines
Chen, Yi,Chen, Deng-Gao,Chen, Yi-An,Wu, Cheng-Ham,Chang, Kai-Hsin,Meng, Fan-Yi,Chen, Meng-Chi,Lin, Jia-An,Huang, Chun-Ying,Su, Jianhua,Tian, He,Chou, Pi-Tai
, p. 16755 - 16764 (2019)
With the aim of generalizing the structure–properties relationship of bending heterocyclic molecules that undergo prominent photoinduced structural planarization (PISP), a series of new dihydrodibenzo[ac]phenazine derivatives in which one nitrogen atom is replaced by oxygen (PNO), sulfur (PNS), selenium (PNSe), or dimethylmethanediyl (PNC) was strategically designed and synthesized. Compounds PNO, PNS, and PNSe have significantly nonplanar geometries in the ground state, which undergo PISP to give a planarlike conformer and hence a large emission Stokes shift. A combination of femtosecond early relaxation dynamics and computational approaches established an R*→I* (intermediate)→P* sequential kinetic pattern for PNS and PNSe, whereas PNO undergoes R*→P* one-step kinetics. The polarization ability of the substituted heteroatoms, which is in the order OSSe, correlates with their increase in π conjugation, and hence the Stokes shift of the emission is in the order PNOPNSPNSe. Compound PNSe with the largest PISP barrier was shown to be a highly sensitive viscosity probe. Further evidence for heteroatom-harnessing PISP is given by PNC, in which the dimethylmethanediyl substituent lacks lone pair electrons for π extension, showing the normal emission of the bent structure. The results led to the conclusion that PISP is ubiquitous in dihydrodibenzo[ac]phenazines, for which the driving force is elongation of the π delocalization to gain stabilization in the excited state.
Organic compound, and electronic element and electronic device using same
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Paragraph 0150-0152; 0155, (2021/07/14)
The invention relates to an organic compound. The structure of the organic compound is shown as a formula I. When the organic compound is used as a hole adjustment layer material of an electronic element, driving voltage can be reduced, the luminous efficiency of a device can be improved, and the service life of the device can be prolonged.
Organic electroluminescent compound and preparation method thereof, and organic electroluminescent device
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Paragraph 0049-0053, (2020/04/22)
The invention discloses an organic electroluminescent compound and a preparation method thereof, and an organic electroluminescent device, and belongs to the field of chemical synthesis and photoelectric materials, wherein the structural general formula of the organic electroluminescent compound is defined in the specification, and in a formula I, L is one selected from a chemical bond, substituted or unsubstituted C6-C30 aryl and substituted or unsubstituted C3-C30 heteroaryl, X is a heteroatom, and Ar1 and Ar2 are respectively and independently selected from substituted or unsubstituted C1-C30 alkyl, substituted or unsubstituted C6-C30 aryl, substituted or unsubstituted C3-C30 heteroaryl, substituted or unsubstituted C3-C30 arylamino, substituted or unsubstituted C3-C30 aliphatic amino and single ring or multi-ring formed by linking adjacent substituent groups. According to the invention, with the application of the organic electroluminescent compound as the material of the light-emitting auxiliary layer and/or hole transport layer of an organic electroluminescent device, the driving voltage of the organic electroluminescent device can be remarkably reduced, the light-emitting efficiency of the organic electroluminescent device is improved, and the service life of the organic electroluminescent device is prolonged.