947-73-9

Usage

Uses

Used in Biochemical Research:
9-Aminophenanthrene is used as a model ligand for studying the binding interactions within the active site of CYP(eryF), a cytochrome P450 enzyme. This application aids in understanding the enzyme's substrate specificity and catalytic mechanisms.
Used in Analytical Chemistry:
9-Aminophenanthrene serves as a fluorescent-labeling reagent for free fatty acids (FFA). This allows for the examination and detection of these lipids through high-performance liquid chromatography (HPLC), providing a valuable tool for lipid analysis and research.

InChI:InChI=1/C14H11N/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H,15H2

Upstream product

• 573-17-1 9-bromophenanthrene 
• 19853-10-2 2-(biphenyl-2-yl)acetonitrile 
• 484-17-3 9-Phenanthrol 
• 954-46-1 9-nitrophenanthrene 
• 17024-21-4 9-Bromo-10-nitrophenanthrene 
• 60883-93-4 5-azidophenanthroline 
• 67464-46-4 1a,9b-dihydro-1H-phenanthro<9,10-b>azirine 
• 85-01-8 phenanthrene 
• 75-05-8 acetonitrile 
• 157366-46-6 2-(o-Tolyl)benzonitrile 
• 7647-01-0 hydrogenchloride 
• 64-19-7 acetic acid 
• 7664-41-7 ammonia 
• 10034-85-2 hydrogen iodide 

Downstream Products

• 4235-09-0 9-(N-acetylamino)phenanthrene 
• 302595-31-9 benzylidene-[9]phenanthryl-amine 
• 81593-08-0 N-9-phenanthrenylbenzamide 
• 16269-40-2 N-9-phenanthrenyl-9-phenanthrenamine 
• 88090-59-9 9H-tetrabenzocarbazole 
• 217-65-2 dibenzo[f,h]quinoline 
• 201-67-2 13H-13-aza-indeno[1,2-l]phenanthrene 
• 1609083-22-8 C₃₄H₂₄N₂ 
• 71-43-2 benzene 
• 1609083-26-2 C₂₀H₁₄BrN 
• 92-52-4 biphenyl 
• 1609083-24-0 10,10'-([1,1'-biphenyl]-4,4'-di-yl)bis(phenanthren-9-amine) 
• 3920-79-4 N-phenyl-N-(9-phenanthryl)amine 

Relevant academic research and scientific papers

MONO AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICE INCLUDING THE SAME

An organic electroluminescent device includes a monoamine derivative represented by Formula 1: In Formula 1, Ar1 may be represented by Formula 2; Ar2 may be a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, wherein the substituent of Ar2 is an unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring; Ar1 and Ar2 may be different from each other; m may be an integer from 0 to 4; and R1 may be a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, and when m is 2 or more, a plurality of R1 may combine to form a ring:

Photocatalytic C-H Amination of Aromatics Overcoming Redox Potential Limitations

We report the photocatalytic C-H amination of aromatics overcoming redox potential limitations. Radical cations of aromatic compounds are generated photocatalytically using Ru(phen)3(PF6)2, which has a reduction potential at a high oxidation state (Ered(RuIII/RuII) = +1.37 V vs SCE) lower than the oxidation potentials of aromatic substrates (Eox = +1.65 to +2.27 V vs SCE). The radical cations are trapped with pyridine to give N-arylpyridinium ions, which were converted to aromatic amines.

Direct conversion of phenols into primary anilines with hydrazine catalyzed by palladium

Primary anilines are essential building blocks to synthesize various pharmaceuticals, agrochemicals, pigments, electronic materials, and others. To date, the syntheses of primary anilines mostly rely on the reduction of nitroarenes or the transition-metal-catalyzed Ullmann, Buchwald-Hartwig and Chan-Lam cross-coupling reactions with ammonia, in which non-renewable petroleum-based chemicals are typically used as feedstocks via multiple step syntheses. A long-standing scientific challenge is to synthesize various primary anilines directly from renewable sources. Herein, we report a general method to directly convert a broad range of phenols into the corresponding primary anilines with the cheap and widely available hydrazine as both amine and hydride sources with simple Pd/C as the catalyst.

Deacetylative Amination of Acetyl Arenes and Alkanes with C-C Bond Cleavage

The Br?nsted acid-catalyzed synthesis of primary amines from acetyl arenes and alkanes with C-C bond cleavage is described. Although the conversion from an acetyl group to amine has traditionally required multiple steps, the method described herein, which uses an oxime reagent as an amino group source, achieves the transformation directly via domino transoximation/Beckmann rearrangement/Pinner reaction. The method was also applied to the synthesis of γ-aminobutyric acids, such as baclophen and rolipram.

PRODUCTION METHOD OF PRIMARY AMINE COMPOUND

PROBLEM TO BE SOLVED: To provide a simple production method of a primary amine compound unnecessary for complicated procedures and toxic sodium azide or the like. SOLUTION: A production method of a primary amine compound includes a step for reacting a ketone compound and an oxime compound in the presence of alcohol and an acid catalyst. Preferably, the acid catalyst is hydrochloric acid, sulfuric acid, methanesulfonic acid, camphorsulfonic acid, a tosyl acid hydrate, trifluoromethane sulfonic acid or a boron trifluoride diethyl ether complex. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT

Aryl amine derivatieves and organic electroluminescent device including the same

Provided is an arylamine derivative that effectively absorbs a high-energy external light source in a UV region and minimizes damage to organic matter inside an organic electroluminescent device, thereby contributing to a substantial improvement in the lifespan of the organic electroluminescent device. An organic electroluminescent device according to the present invention comprises a first electrode, a second electrode, and one or more organic material layers provided between the first electrode and the second electrode. The organic material layer contains an arylamine derivative representedby chemical formula 1. In the chemical formula 1, the definition of each substituent is the same as the definition in the specific embodiment of the invention.

Material for organic electroluminescent device and organic electroluminescent device using the same

A material for an organic electroluminescent device and an organic electroluminescent device including the same, the material including a monoamine compound represented by the following Formula 1:

Material for organic electroluminescent device and organic electroluminescent device using the same

A novel and improved material for an organic electroluminescent device includes at least one monoamine compound represented by any one of the following Formulae I to III: In Formulae I to III, Ar is a substituted or unsubstituted aryl group having 6 to 50 carbon atoms for forming a ring. The organic electroluminescent device including the material may have improved emission life.

Cobalt-Catalyzed Direct Carbonylative Synthesis of Free (NH)-Benzo[ cd]indol-2(1 H)-ones from Naphthylamides

A cobalt-catalyzed C-H carbonylation of naphthylamides for the synthesis of benzo[cd]indol-2(1H)-one scaffolds has been developed. The reaction employs a traceless directing group and uses benzene-1,3,5-triyl triormate as the CO source, affording various free (NH)-benzo[cd]indol-2(1H)-ones in moderate to high yields (up to 88%). Using this protocol, the total synthesis of BET bromodomain inhibitors A and B was accomplished as well.

AMINATION AND HYDROXYLATION OF ARYLMETAL COMPOUNDS

In one aspect, the present disclosure provides methods of preparing a primary or secondary amine and hydroxylated aromatic compounds. In some embodiments, the aromatic compound may be unsubstituted, substituted, or contain one or more heteroatoms within the rings of the aromatic compound. The methods described herein may be carried out without the need for transition metal catalysts or harsh reaction conditions.