3949-80-2

Upstream product

• 64-67-5 diethyl sulfate 
• 1752-24-5 4,4'-dihydroxydiphenylamine 
• 74-96-4 ethyl bromide 
• 23510-92-1 4-ethoxycyclohexan-1-one 
• 540-38-5 p-Iodophenol 
• 699-08-1 1-ethoxy-4-iodobenzene 
• 156-43-4 4-Ethoxyaniline 
• 588-96-5 4-bromoethoxybenzene 
• 106-41-2 4-bromo-phenol 

Relevant academic research and scientific papers

9,9′-bifluorenylidene derivatives as novel hole-transporting materials for potential photovoltaic applications

Novel 9,9′-bifluorenylidene derivatives were designed to study the effect of alkyl chain length on selected physical properties. The structure of the synthesized compounds was confirmed by using NMR spectroscopy (1H, 13C, H–H COSY, H–C HMQC, H–C HMBC) and elemental analysis. They showed high thermal stability and undergo decomposition in the range of 388–400 °C. As was revealed by DSC investigations, they can be converted from crystalline to amorphous materials with relatively high glass transition temperature. The replacement of the alkyl chains from ethyl to butyl resulted in a significant negative impact on melting and glass transition temperatures. The synthesized derivatives undergo reversible electrochemical oxidation and reduction and showed a very low energy band gap (1.47 and 1.79 eV). They intensively absorb the light up 550 nm and also exhibited a week absorption band in the range of 550–750 nm. Their hole transporting ability was tested in perovskite solar cells. Additionally, the effect of the doping concentration of Li+ on photovoltaic device performance for these compounds was investigated. It should be stressed found that 9,9′-bifluorenylidene derivative substituted with ethyl units applied as hole transporting materials in perovskite solar cells demonstrated the highest device efficiency of 7.33% higher than of the spiro-OMeTAD utilized for preparation of the reference cell (4.40%).

Organic hole transport material and preparation method and application thereof

The invention provides an organic hole transport material and a preparation method and application thereof. The structural general formula of the organic hole transport material is shown in the specification, and in the formula, R is ethyl, propyl, isopropyl or butyl. The preparation method is simple and easy to implement, the structure is definite, and the prepared organic hole transport materialhas high photoelectric conversion efficiency and can be applied to perovskite solar cells.

Formal arylation of NH3 to produce diphenylamines over supported Pd catalysts

In the presence of supported Pd nanoparticle catalysts, e.g., Pd/Al2O3, various diphenylamines could be synthesized through acceptorless formal arylation using NH3 or its surrogates, e.g., urea, as nitrogen sources and cyclohexanones as arylation sources. The observed catalysis was truly heterogeneous, and the catalyst was reusable with retention of its high catalytic performance.