39508-15-1Relevant academic research and scientific papers
Magnesiation of electron-rich aryl bromides and their use in nickel-catalyzed cross-coupling reactions
Lau, Stephen Y. W.,Hughes, Greg,O'Shea, Paul D.,Davies, Ian W.
, p. 2239 - 2242 (2008/02/03)
Electron-rich aryl bromides are rapidly converted to the corresponding lithium triarylmagnesiates with (n-Bu)3MgLi, which undergo efficient nickel-catalyzed Kumada-Corriu cross-coupling reactions with a variety of aryl and alkenyl bromides, chlorides, tosylates, and triflates.
Pinacolboratamethyl-enetriphenylphosphonium iodide, a new methylene transfer reagent
Al-Aziz Quntar, Abed,Srebnik, Morris
, p. 2575 - 2579 (2007/10/03)
The title compound is easily prepared and reacts with various aldehydes and ketone. The reagent is compatible with free hydroxy groups. Yields with various aldehydes and ketones are in 50- > 99% range. Both aliphatic, aromatic and unsaturated carbonyls react.
