39623-95-5

Upstream product

• 108-22-5 Isopropenyl acetate 
• 93-55-0 1-phenyl-propan-1-one 
• 108-24-7 acetic anhydride 

Downstream Products

• 2114-29-6 (R)-1-phenylpropyl acetate 
• 69843-69-2 2-Benzoyl-3-aethoxybutan 
• 128271-44-3 3,3,3-trifluoro-2-methyl-1-phenylpropan-1-one 
• 2114-29-6 (S)-1-phenylpropyl acetate 
• 269725-81-7 3-(p-chlorophenyl)-3-hydroxy-1-phenylpropan-1-one 
• 128814-77-7 3-hydroxy-3-(4-methylphenyl)-1-phenylpropan-1-one 
• 42052-51-7 3-hydroxy-1,3-diphenylpropan-1-one 
• 13505-39-0 3-hydroxy-1-phenyl-butan-1-one 
• 43108-74-3 3-hydroxy-3-methyl-1-phenyl-1-butanone 
• 14723-74-1 2-(methylsulfonyl)-1-phenylpropan-1-one 
• 14195-15-4 α-(p-methylbenzenesulfonyl)propiophenone 
• 77092-54-7 (E)-2-(1-phenylprop-1-en-1-yl)-1H-indole 
• 13266-91-6 (Z)-1-phenylprop-1-en-1-yl acetate 
• 54266-11-4 (t-C₄H₉)2SbOC(C₆H₅)=CHCH₃ 

Relevant academic research and scientific papers

Highly efficient Cu(I)-catalyzed trifluoromethylation of aryl(heteroaryl) enol acetates with CF3 radicals derived from CF3SO 2Na and TBHP at room temperature

An efficient method for the Cu(I)-catalyzed synthesis of α-trifluoromethyl ketones via the addition of CF3 to aryl(heteroaryl) enol acetates by using the readily available CF 3SO2Na (Langlois reagent) has been developed. The reaction is experimentally simple and carried out at room temperature, providing good to excellent yields with wide functional group tolerance.

Lipase/aluminum-catalyzed dynamic kinetic resolution of secondary alcohols

(Chemical Equation Presented) Racemization wanted: The dynamic kinetic resolution of secondary alcohols can be achieved by a simple and readily available catalyst system. Substrate racemization is effected at room temperature by a combination of (racemic) 1,1′-bi-2-naphthol (binol) or 2,2′-biphenol with AIMe3, and a lipase performs enantiospecific acylation (see scheme).

Investigations into the regioselective C-deuteration of acyclic and exocyclic enolates

Results are reported on the regioselective C-deuteration of a series of related acyclic and exocyclic enolates derived from substituted aryl ketones. We comment on factors, such as the presence of additives and the structural nature of the enolate, that influence the observed C-deuteration and discuss the role of the deuterium donor. ( Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).