39623-95-5Relevant articles and documents
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Moon,Campbell
, p. 470 (1966)
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Lipase/aluminum-catalyzed dynamic kinetic resolution of secondary alcohols
Berkessel, Albrecht,Sebastian-Ibarz, M. Luisa,Mueller, Thomas N.
, p. 6567 - 6570 (2007/10/03)
(Chemical Equation Presented) Racemization wanted: The dynamic kinetic resolution of secondary alcohols can be achieved by a simple and readily available catalyst system. Substrate racemization is effected at room temperature by a combination of (racemic) 1,1′-bi-2-naphthol (binol) or 2,2′-biphenol with AIMe3, and a lipase performs enantiospecific acylation (see scheme).