39626-32-9Relevant academic research and scientific papers
Iron-catalyzed oxidation of tertiary amines: Synthesis of β-1,3-dicarbonyl aldehydes by three-component C-C couplings
Liu, Weiping,Liu, Jinhua,Ogawa, Daisuke,Nishihara, Yasushi,Guo, Xingwei,Li, Zhiping
, p. 6272 - 6275 (2011)
β-1,3-Dicarbonyl aldehydes were synthesized by iron-catalyzed oxidative reactions between 1,3-dicarbonyl compounds and two molecules of tertiary amines in the presence of tert-butyl hydroperoxide (TBHP). α,β-Unsaturated aldehydes generated by tertiary ami
A new route to 2-alkenyl-1,3-dicarbonyl compounds, intermediates in the synthesis of dihydrofurans
Antonioletti, Roberto,Bovicelli, Paolo,Malancona, Savina
, p. 589 - 596 (2007/10/03)
A two step synthetic strategy for obtaining 2-alkenyl-1,3-dicarbonyl compounds from the corresponding 1,3-dicarbonyl compounds is reported. The method is based on a Knoevenagel condensation and a Michael addition using a high order organocuprate procedure, and proves to be of general value. Obtained compounds are useful starting materials for the synthesis of furan derivatives.
