351031-95-3

Upstream product

• 123-73-9 trans-Crotonaldehyde 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 123-73-9 crotonaldehyde 
• 7087-68-5 N-ethyl-N,N-diisopropylamine 
• 75-07-0 acetaldehyde 
• 109-89-7 diethylamine 
• 39626-32-9 2-benzoyl-but-2-enoic acid ethyl ester 
• 772-54-3 N,N-diethylbenzylamine 
• 1620-14-0 1-(diethylamino)propan-2-one 
• 150-77-6 N,N,N',N'-Tetraethylethylenediamine 
• 616-39-7 N,N-diethylnmethylamine 

Downstream Products

• 58787-21-6 ethyl 2-phenyl-4-methyl-3-pyridinecarboxylate 
• 58786-39-3 Indeno<1,2,3ij><2,7>naphthyridine 

Relevant academic research and scientific papers

Polycyclic Aromatic Alkaloids, II: Synthesis of Onychine and Eupolauridine

The total synthesis of onychine (5) is improved by a new approach to the biaryl 4.Eupolauridine (7) is prepared from 5 in a one pot synthesis via the enamine 6.

Iron-catalyzed oxidation of tertiary amines: Synthesis of β-1,3-dicarbonyl aldehydes by three-component C-C couplings

β-1,3-Dicarbonyl aldehydes were synthesized by iron-catalyzed oxidative reactions between 1,3-dicarbonyl compounds and two molecules of tertiary amines in the presence of tert-butyl hydroperoxide (TBHP). α,β-Unsaturated aldehydes generated by tertiary ami

Utilization of nonionic bases in water as a highly efficient organocatalytic system for Michael addition of β-ketoesters

Michael addition of various β-ketoesters with several Michael acceptors in water containing 5 mol% of a nonionic base such as phosphazenes, guanidines, and more classical nitrogen containing derivatives or triphenyl phosphine results in high yield convers

P-BEMP: A new efficient and commercially available user-friendly and recyclable heterogeneous organocatalyst for the Michael addition of 1,3-dicarbonyl compounds

Michael addition of 1,3-dicarbonyls with various Michael acceptors has been found to be catalyzed by commercially available, user-friendly and recyclable N-phenyl-tris(dimethylamino)iminophosphorane immobilized on polystyrene resin (P-BEMP). The reaction

Highly efficient phosphazene base-catalyzed Michael addition of β-ketoesters in water

Michael addition of various β-ketoesters with several Michael acceptors in water containing 10 mol% of N-phenyltris(dimethylamino)iminophosphorane results in high yield conversion to the corresponding adducts.

LITHIUM HYDROXIDE-CATALYZED CONJUGATE ADDITION OF β-DICARBONYL COMPOUNDS

Lithium hydroxide proves to be a very efficient catalyst for Michael addition of β-dicarbonyl compounds 1.The application of the methodology to α,γ-diketo esters and α-keto γ-diesters 4 allows an easy approach to δ-diketones and δ-keto esters 5, respectiv