351031-95-3

Basic information

• Product Name: ethyl 2-benzoyl-3-methyl-5-oxo-pentanoate
• Synonyms: ethyl 2-benzoyl-3-methyl-5-oxo-pentanoate
• CAS NO: 351031-95-3
• Molecular Weight: 262.306
• Mol File: 351031-95-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: ethyl 2-benzoyl-3-methyl-5-oxo-pentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-benzoyl-3-methyl-5-oxo-pentanoate(351031-95-3)
• EPA Substance Registry System: ethyl 2-benzoyl-3-methyl-5-oxo-pentanoate(351031-95-3)

Safety Data

• Hazardous Substances Data: 351031-95-3(Hazardous Substances Data)

Upstream product

• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 123-73-9 crotonaldehyde 
• 7087-68-5 N-ethyl-N,N-diisopropylamine 
• 75-07-0 acetaldehyde 
• 109-89-7 diethylamine 
• 39626-32-9 2-benzoyl-but-2-enoic acid ethyl ester 
• 772-54-3 N,N-diethylbenzylamine 
• 1620-14-0 1-(diethylamino)propan-2-one 
• 150-77-6 N,N,N',N'-Tetraethylethylenediamine 
• 616-39-7 N,N-diethylnmethylamine 
• 123-73-9 trans-Crotonaldehyde 

Downstream Products

• 58786-39-3 Indeno<1,2,3ij><2,7>naphthyridine 
• 58787-21-6 ethyl 2-phenyl-4-methyl-3-pyridinecarboxylate 

Relevant articles and documents

Polycyclic Aromatic Alkaloids, II: Synthesis of Onychine and Eupolauridine

The total synthesis of onychine (5) is improved by a new approach to the biaryl 4.Eupolauridine (7) is prepared from 5 in a one pot synthesis via the enamine 6.

Utilization of nonionic bases in water as a highly efficient organocatalytic system for Michael addition of β-ketoesters

Michael addition of various β-ketoesters with several Michael acceptors in water containing 5 mol% of a nonionic base such as phosphazenes, guanidines, and more classical nitrogen containing derivatives or triphenyl phosphine results in high yield convers

Highly efficient phosphazene base-catalyzed Michael addition of β-ketoesters in water

Michael addition of various β-ketoesters with several Michael acceptors in water containing 10 mol% of N-phenyltris(dimethylamino)iminophosphorane results in high yield conversion to the corresponding adducts.