39647-93-3Relevant articles and documents
A highly efficient synthesis of prostaglandin intermediates possessing the 15S configuration
Noyori,Tomino,Nishizawa
, p. 5843 - 5844 (1979)
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Synthesis of a pyrazole prostacyclin
Suzuki,Sugiura,Noyori
, p. 4817 - 4820 (1982)
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Fully stereocontrolled syntheses of 3-oxacarbacyclin and carbacyclin by the conjugate addition-azoalkene-asymmetric olefination strategy
Kim, Mikhail,Gais, Hans-Joachim
, p. 4642 - 4650 (2007/10/03)
A fully stereocontrolled synthesis of 3-oxacarbacyclin (3) and a formal synthesis of carbacyclin (2) are described. The syntheses are based on the conjugate addition-azoalkene-asymmetric olefination strategy. Its key features are (1) the stereoselective e
Catalytic Asymmetric Addition of Polyfunctional Dialkylzincs to β-Stannylated and β-Silylated Unsaturated Aldehydes
Ostwald, Roswitha,Chavant, Pierre-Yves,Stadtmueller, Heinz,Knochel, Paul
, p. 4143 - 4153 (2007/10/02)
The addition of functionalized dialkylzincs to readily available β-stannylated or β-silylated unsaturated aldehydes in the presence of a catalytic amount of (1R,2R)-1,2-bis(trifluorosulfonamido)cyclohexane (8 mol percent) provides chiral allylic alcohols