104995-81-5

Upstream product

• 39647-93-3 (S)-(E)-(+)-1-Iodo-1-octen-3-ol 
• 14371-10-9 (E)-3-phenylpropenal 
• 14402-93-8 dipentylzinc 
• 100-42-5 styrene 
• 26054-67-1 (-)-7α-hydroxy-6β-(3α-hydroxy-1E-octenyl)-cis-2-oxabicyclo<3.3.0>octan-3-one 
• 133302-11-1 ((2R,3S)-3-Pentyl-2-trimethylsilanyl-oxiranyl)-methanol 
• 29478-39-5 (E)-1-phenyloct-1-en-3-one 
• 39178-64-8 (E)-1-iodo-1-octen-3-one 
• 39198-04-4 (E)-1-chloro-oct-1-en-3-one 
• 104995-73-5 (S)-((2R,3S)-3-Pentyl-2-trimethylsilanyl-oxiranyl)-phenyl-methanol 
• 87922-58-5 (Z)-2-Trimethylsilanyl-oct-2-en-1-ol 
• 104995-68-8 (2S,3S)-3-Pentyl-2-trimethylsilanyl-oxirane-2-carbaldehyde 
• 15719-56-9 1-heptynyltrimethylsilane 
• 104995-78-0 (1S,2R,3S)-1-Phenyl-2-trimethylsilanyl-octane-1,3-diol 

Relevant academic research and scientific papers

Absolute stereochemistry of allylic alcohols, amines, and other ene moieties: A microscale cross metathesis/exciton chirality protocol

A microscale chemical/chiroptical protocol for the determination of absolute configurations of allylic alcohols, amines, and related systems has been developed. The method is based on the conversion of the double bonds into a styrene, λmax 248

Cobalt-Catalyzed Enantiospecific Dynamic Kinetic Cross-Electrophile Vinylation of Allylic Alcohols with Vinyl Triflates

Asymmetric cross-electrophile coupling has emerged as a promising tool for producing chiral molecules; however, the potential of this chemistry with metals other than nickel remains unknown. Herein, we report a cobalt-catalyzed enantiospecific vinylation

Fluorescence detected exciton coupled circular Dichroism: Development of new fluorescent reporter groups for structural studies

In collaboration with Jasco Corporation we have recently developed an FDCD (fluorescence detected circular dichroic) instrument J-465, which eliminates the photoselection artifacts and efficiently collects the emitted light from the sample solution based

Catalytic asymmetric synthesis of protected α-hydroxy aldehydes and related 1,2-difunctional chiral building blocks. An enantioselective synthesis of (-)-exo- and (-)-endo-brevicomin

Chiral allylic alcohols which were prepared by the addition of functionalized dialkylzincs to α,β-unsaturated aldehydes in good to excellent enantioselectivity, were converted to protected α-hydroxy aldehydes and 1,2-amino alcohols without loss of enantio

A HIGHLY EFFICIENT SYNTHESIS OF OPTICALLY PURE γ-IODO ALLYLIC ALCOHOLS AND THEIR CONVERSION INTO VARIOUS OPTICALLY ACTIVE ALLYLIC ALCOHOLS

Kinetic resolution of γ-iodo allylic alcohols 1 by the Sharpless asymmetric epoxidation reaction proceeds with very large rate differences for the two enantiomers, thus providing a highly efficient method for preparation of optically pure 1.The alcohols 1

Synthesis of Optically Active β,γ-Epoxy Alcohols and Secondary Allylic Alcohols via Diastereoselective Addition of α-Trimethylsilyl-α,β-epoxy Aldehydes with Organometallic Compounds

Optically active α-trimethylsilyl-α,β-epoxy aldehydes 3 react with various Grignard reagents or organolithium compounds highly stereoselectively to give erythro adducts 4, which can be readily converted into β,γ-epoxy secondary alcohols 1 or secondary allylic alcohols 2.