3968-41-0Relevant academic research and scientific papers
[InCl4]-catalyzed addition of hydrazones to β-diketones: An efficient regioselective synthesis of pyrazoles and pyrazole-fused cyclohexanones
Safaei, Shirin,Mohammadpoor-Baltork, Iraj,Khosropour, Ahmad Reza,Moghadam, Majid,Tangestaninejad, Shahram,Mirkhani, Valiollah,Khavasi, Hamid Reza
, p. 1086 - 1090 (2013/07/11)
The Lewis acidic room-temperature ionic liquid, [bmim][InCl4], was found to be an efficient catalyst for the regio-selective synthesis of fully substituted pyrazoles and pyrazole-fused cyclohexanones through condensation of hydrazones with symm
1,3-Dipolar Cycloaddition of Four Hydrazonoyl Chlorides to β-Diketones and α,β-Unsaturated Ketones
Albar, Hassan A.
, p. 872 - 889 (2007/10/03)
The 1,3-dipolar cycloaddition of four hydrazonoyl chloride derivatives with the sodium salt of unsymmetrical β-diketones (benzoylacetone) offers a versatile method for the regioselective synthesis of 2H-pyrazoles in a similar fashion to the cycloaddition of the nitrilimides with α,β-unsaturated ketones and esters. The structures of the prepared isomeric pyrazole and pyrazoline derivatives were established by spectroscopic and chemical methods.
