39807-65-3Relevant academic research and scientific papers
A Mild Multi-Component Reaction for the Synthesis of 4,5-Disubstituted 1 H -1,2,3-Triazoles from Phosphonium Salts, Aldehydes, and Sodium Azide
Wu, Guang-Long,Wu, Qin-Pei
, p. 2768 - 2774 (2018/05/15)
A mild and metal-free multi-component reaction to synthesize 4,5-disubstituted 1 H -1,2,3-triazoles from phosphonium salts, aldehydes, and sodium azide is described. The process undergoes an organocatalyzed coupling of formyl group with phosphonium to for
Synthesis of 4-aryl-1H-1,2,3-triazoles through TBAF-catalyzed [3 + 2] cycloaddition of 2-aryl-1-nitroethenes with TMSN3 under solvent-free conditions
Amantini, David,Fringuelli, Francesco,Piermatti, Oriana,Pizzo, Ferdinando,Zunino, Ennio,Vaccaro, Luigi
, p. 6526 - 6529 (2007/10/03)
TBAF-catalyzed [3 + 2] cycloaddition reactions of 2-aryl-1-cyano- or 2-aryl-1-carbethoxy-1-nitroethenes 1 with TMSN3 under SFC allow the corresponding 4-aryl-5-cyano- or 4-aryl-5-carbethoxy-1H-1,2,3-triazoles 2 to be prepared under mild reactio
THERMOLYSIS AND PHOTOLYSIS OF 4-DIAZO-1,2,3-TRIAZOLES IN BENZENOID SOLVENTS, SYSTEMS WHICH REVEAL DECOMPOSITION OF DIAZO COMPOUNDS TO CARBENES TO DIAZO COMPOUNDS TO CARBENES.
Hui, H. K.-W.,Shechter, H.
, p. 5115 - 5118 (2007/10/02)
4-Diazo-1,2,3-triazoles thermolyze and photolyze to 4H-1,2,3-triazolylidenes which (1) convert benzenes to 4-phenyl-1,2,3-triazoles or/and (2) isomerize to α-diazonitriles which react carbenically with benzenes by addition, ring-expansion or substitution processes.
