39828-57-4 Usage
Uses
Used in Catalyst Applications:
Nickel(II) tetramethoxyphenylporphyrin is utilized as a catalyst in various organic reactions, such as oxidation and reduction processes. Its ability to facilitate electron transfer makes it a valuable component in enhancing the efficiency and selectivity of these reactions.
Used in Biomedical Research:
In the field of biomedical research, Nickel(II) tetramethoxyphenylporphyrin has been studied for its potential as a photosensitizer in photodynamic therapy for cancer treatment. Its unique structure allows it to absorb light at specific wavelengths and generate reactive oxygen species, which can selectively destroy cancer cells while minimizing damage to healthy tissues.
Used in Chemical and Biological Applications:
Due to its distinctive properties, Nickel(II) tetramethoxyphenylporphyrin is also employed in a wide range of chemical and biological applications, where its capacity to interact with other molecules and participate in electron transfer processes is highly beneficial.
Check Digit Verification of cas no
The CAS Registry Mumber 39828-57-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,9,8,2 and 8 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 39828-57:
(7*3)+(6*9)+(5*8)+(4*2)+(3*8)+(2*5)+(1*7)=164
164 % 10 = 4
So 39828-57-4 is a valid CAS Registry Number.
39828-57-4Relevant academic research and scientific papers
Insertion of Ni(I) into Porphyrins at Room Temperature: Preparation of Ni(II)porphyrins, and Ni(II)chlorins and Observation of Hydroporphyrin Intermediates
Peters, Morten K.,Herges, Rainer
, p. 3177 - 3182 (2018/03/26)
Reduced Nickel porphyrins play an important role as enzymatic cofactors in the global carbon cycle (cofactor F430), and as powerful catalysts in solar-to-fuel-processes such as the hydrogen evolution reaction, and the reduction of CO and CO2. The preparation of Ni(II)porphyrins requires harsh conditions, and characterization of the reduced species is intricate. We present a very mild, convenient, and high yielding method of inserting Ni into electron rich, and electron deficient porphyrins which at the same time gives access to to Ni(II) phlorins and Ni(II)chlorins and Ni(II)porphyrins.
Synthesis of calix[3]dipyrrins by a modified Lindsey protocol
Inoue, Mitsunori,Ikeda, Chusaku,Kawata, Yuji,Venkatraman, Sundararaman,Furukawa, Ko,Osuka, Atsuhiro
, p. 2306 - 2309 (2008/03/12)
(Figure Presented) Bowled over: Calix[3]dipyrrins were synthesized from pyrrole and aryl aldehyde precursors by the Lindsey protocol, modified by the presence of a small amount of water. These bowl-shaped macrocycles can accommodate three metal (M) ions such as NiII and CuII in a hexagonal M3O3 manner (see structure; Cu green, N blue, O red, C black).
