39945-18-1Relevant academic research and scientific papers
Circular linkage of intramolecular multi-hydrogen bonding frameworks through nucleophilic substitutions of β-dicarbonyls onto cyanuric chloride and subsequent tautomerisation
Awatani, Ayano,Suzuki, Masaaki
, p. 39033 - 39036 (2020)
Nucleophilic substitution reactions of cyanuric chloride with a series of β-dicarbonyls give triply β-dicarbonyl-embedded 1,3,5-triazines. Their subsequent but spontaneous tautomeric transformation leads to circularly linked, intramolecular, multi-hydrogen bonding networks. Their structural elucidation by X-ray crystallography showed elongated double bonds and shortened single bonds. This is likely due to a resonance hybrid formed via tautomerisation and simultaneous proton transfer. This journal is
s-TRIAZINE DERIVATIVES 2. A STUDY OF THE REACTIONS OF SODIOMALONIC ESTER WITH 2,4-DICHLORO-6-METHOXY-s-TRIAZINE AND CYANURYL CHLORIDE
Vakhatova, G. M.,Yakhontov, L. N.
, p. 433 - 436 (2007/10/02)
2,4-Dichloro-6-methoxy-s-triazine reacts with sodiomalonic ester in dimethylformamide at room temperature to give 2,4-bis(diethoxycarbonylmethylene)-6-methoxy-1,2,3,4-tetrahydro-s-triazine which forms a sodium salt with caustic soda.Under similar conditions cyanuryl chloride forms 2,4,6-tris(dimethoxycarbonylmethylene)hexahydro-s-triazine and 2-chloro-4,6-bis(diethoxycarbonylmethylene)tetrahydro-s-triazine.
