400-52-2Relevant articles and documents
Oxidative Fragmentation of Saturated Hydrocarbons. II. Oxidative Fragmentation of 1,3,5-Trimethyladamantane
Krasutskii,Baula,Botov
, p. 985 - 989 (2007/10/03)
Oxidation of 1,3,5-trimethyladamantane and 7-hydroxy-1,3,5-trimethyladamantane by perfluoroperoxybutyric acid in perfluorobutyric acid is accompanied by fragmentation of the adamantane polyhedron with formation of cis-1,3,5-trimethyl-cis-3,5-bis(perfluorobutanoyloxymethyl)cyclohexaneacetic acid. The reaction of tert-butyl alcohol with perfluoroperoxyacetic acid simulates well the process of oxidative fragmentation of adamantane and its derivatives. The mechanisms of these transformations are discussed.
CONVERSION OF BICYCLOPENTANE INTO 2,3-DIOXABICYCLOHEPTANE VIA t-BUTYL PEROXYMERCURIATION
Bloodworth, A. J.,Hargreaves, Neville
, p. 2783 - 2784 (2007/10/02)
Bicyclopentane has been converted in 45 percent yield into 2,3-dioxabicycloheptane by the sequence t-butyl peroxymercuriation, iodomercuriation, epimerisation of the resultant 1-t-butylperoxy-3-iodocyclopentane, and reaction of the trans isomer with silver trifluoroacetate.
Oxidative Displacement of Halogen from Alkyl Halides by Phenyliodine(III) Dicarboxylates
Gallos, John,Varvoglis, Anastasios
, p. 1999 - 2002 (2007/10/02)
The reaction of alkyl iodides with aryliodine(III) dicarboxylates affords as the main product the ester derived through substitution of iodine by an acyloxy group; in some cases α-iodoalkyl esters are also formed along with other minor products.Certain reactive bromides and chlorides react along similar lines.The mechanism of these reactions is briefly discussed.