40230-56-6Relevant academic research and scientific papers
An efficient synthesis of chiral β-hydroxy sulfones via Ru-catalyzed enantioselective hydrogenation in the presence of iodine
Wan, Xiaobing,Meng, Qinghua,Zhang, Hongwei,Sun, Yanhui,Fan, Weizheng,Zhang, Zhaoguo
, p. 5613 - 5616 (2007)
Ru-SUNPHOS catalyzed asymmetric hydrogenation of a variety of sulfonyl ketones (R = alkyl, aryl) in the presence of iodine gave enantioenriched hydroxyl sulfones with good catalytic efficiency. Further investigation revealed that the in situ generated anh
Kinetics and mechanism of oxirane formation by darzens condensation of ketones: Quantification of the electrophilicities of ketones
Li, Zhen,Jangra, Harish,Chen, Quan,Mayer, Peter,Ofial, Armin R.,Zipse, Hendrik,Mayr, Herbert
supporting information, p. 5500 - 5515 (2018/05/03)
The kinetics of epoxide formation by Darzens condensation of aliphatic ketones 1 with arylsulfonyl-substituted chloromethyl anions 2 (ArSO2CHCl-) have been determined photometrically in DMSO solution at 20 °C. The reactions proceed v
