40267-41-2Relevant academic research and scientific papers
Recycling of homogeneous catalysts in reactive ionic liquid-solvent-free aminofunctionalizations of alkenes
Fa?bach, Thiemo A.,Kirchmann, Robin,Behr, Arno,Vorholt, Andreas J.
supporting information, p. 5243 - 5249 (2017/11/09)
The catalyst in homogeneously catalyzed aminofunctionalizations is often difficult to recycle, making these reactions expensive on an industrial scale. The use of dimethylammonium dimethylcarbamate (dimcarb) as a reactive ionic liquid provides an elegant solution to this challenge, as it is a substrate and polar phase at the same time. In this work, homogeneously transition-metal catalyzed reactions-specifically hydroamination, telomerization and hydroaminomethylation-are carried out in neat substrates without additional solvents. The ionic character of dimcarb enables the immobilization of the active catalysts in the reactive ionic liquid, using sulfonated ligands. Investigations regarding the hydroamination of 1,3-dienes led to a total turnover number (TTON) of more than 8700 with β-farnesene in 12 repetitive recycling experiments. The telomerization of 1,3-butadiene was carried out over 30 consecutive runs without any loss of activity, resulting in a TTON of more than 90 000.
Reactions of Isoprene with Secondary Amines
Kazantsev, O. A.,Shirshin, K. V.,Danov, S. M.,Afon'shin, G. N.
, p. 300 - 303 (2007/10/03)
Reactions of isoprene with secondary amines in the presence of alkali metals yield isomeric aminoolefins: 1-dialkylamino-3-methyl-2-butenes, 1-dialkylamino-2-methyl-2-butenes, and 1-dialkylamino-3-methyl-1-butenes.The influence of temperature, structure of the secondary amine, amount of catalyst, and molar ratio of the reactants on the yield of aminoolefins and selectivity of their formation has been examined.
