40267-43-4Relevant academic research and scientific papers
Reactions of Isoprene with Secondary Amines
Kazantsev, O. A.,Shirshin, K. V.,Danov, S. M.,Afon'shin, G. N.
, p. 300 - 303 (2007/10/03)
Reactions of isoprene with secondary amines in the presence of alkali metals yield isomeric aminoolefins: 1-dialkylamino-3-methyl-2-butenes, 1-dialkylamino-2-methyl-2-butenes, and 1-dialkylamino-3-methyl-1-butenes.The influence of temperature, structure of the secondary amine, amount of catalyst, and molar ratio of the reactants on the yield of aminoolefins and selectivity of their formation has been examined.
Telomerization of Isoprene with Dialkylamine Catalyzed by Palladium Complexes
Hidai, Masanobu,Mizuta, Haruyoshi,Hirai, Kiyomiki,Uchida, Yasuzo
, p. 2091 - 2092 (2007/10/02)
Telomerization of isoprene with diethylamine in the presence of catalytic amounts of palladium chloride and triphenylphosphine under carbon dioxide and/or using methanol as solvent gave three kinds of 2:1 adducts in good yields, one of which was found to be an adduct of new type.
